Equal volumes of solutions containing 1 mole of an acid and 1 mole of ...
Understanding pH of Acid-Base Mixtures
When equal volumes of solutions containing 1 mole of an acid and 1 mole of a base are mixed, the resultant pH depends on the strength and nature of the acid and base involved. Here's a breakdown of the options provided:
Sodium Hydroxide + Acetic Acid
- Nature of Reactants: Sodium hydroxide (NaOH) is a strong base, while acetic acid (CH3COOH) is a weak acid.
- Reaction Outcome: When mixed, sodium hydroxide will completely neutralize acetic acid, but there will be an excess of hydroxide ions (OH-) because acetic acid doesn't dissociate completely.
- Resulting pH: The excess hydroxide ions will lead to a pH greater than 7, making the solution basic.
Potassium Hydroxide + Sulphuric Acid
- Nature of Reactants: Potassium hydroxide (KOH) is a strong base, and sulfuric acid (H2SO4) is a strong acid.
- Reaction Outcome: This mixture will completely neutralize each other, resulting in a neutral solution if stoichiometrically balanced.
- Resulting pH: The resulting pH will be around 7.
Ammonium Hydroxide + Sulphuric Acid
- Nature of Reactants: Ammonium hydroxide (NH4OH) is a weak base, and sulfuric acid is a strong acid.
- Reaction Outcome: The strong acid will dominate, leading to a solution that is acidic.
- Resulting pH: The pH will be less than 7.
Sodium Hydroxide + Hydrochloric Acid
- Nature of Reactants: Both sodium hydroxide and hydrochloric acid (HCl) are strong.
- Reaction Outcome: They will completely neutralize each other.
- Resulting pH: The resulting pH will be 7, indicating neutrality.
Conclusion
Among the options, only the mixture of sodium hydroxide and acetic acid results in a pH greater than 7 due to the presence of excess hydroxide ions after the weak acid is neutralized.
Equal volumes of solutions containing 1 mole of an acid and 1 mole of ...
Acetic acid (Weak Acid) + Sodium Hydroxide (Strong Base) → Sodium Acetate (Basic)
Sulphuric acid (Strong Acid) + Potassium Hydroxide (Strong Base) → Potassium Sulphate (Neutral)
Sulphuric Acid (Strong Acid) + Ammonium hydroxide (Weak base) → Ammonium sulphate (Acidic)
Hydrochloric Acid (Strong Acid) + Sodium hydroxide (Strong Base) → Sodium Chloride (Neutral)
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