The order of stability of the following tautomeric compond is--: CH2=C...
The order of stability of the tautomeric compounds can be determined by analyzing the resonance structures and the stability of the resulting molecules. Let's analyze each compound in detail:
Compound 1: CH2=COH--CH2--C=O--CH3
- In this compound, the keto form is more stable. The double bond between carbon and oxygen is in conjugation with the carbonyl group, leading to resonance stabilization.
- The enol form, which has a double bond between carbon and oxygen, is less stable due to the lack of resonance stabilization.
Compound 2: CH3--C=O--CH2--C=--CH3
- In this compound, both the keto and enol forms are possible. However, the enol form is more stable due to the presence of a conjugated system.
- The double bond between the two carbons is in conjugation with the carbonyl group, leading to resonance stabilization and increased stability.
Compound 3: CH3--COH=CH--C=O--CH3
- In this compound, the enol form is more stable. The double bond between carbon and oxygen is in conjugation with the carbonyl group, leading to resonance stabilization.
- The keto form is less stable due to the lack of resonance stabilization.
Order of stability: 2 > 3 > 1
Explanation:
- Compound 2 is the most stable due to the presence of a conjugated system. The resonance stabilization provided by the conjugation of the double bond with the carbonyl group increases the stability of the molecule.
- Compound 3 is less stable than compound 2 but more stable than compound 1. The enol form of compound 3 has resonance stabilization due to the conjugation of the double bond with the carbonyl group.
- Compound 1 is the least stable among the three compounds. The keto form of compound 1 has some resonance stabilization due to the conjugation of the double bond with the carbonyl group, but it is not as stable as the enol forms of compounds 2 and 3.
In summary, the order of stability of the tautomeric compounds is as follows: 2 > 3 > 1. Compound 2 is the most stable due to the presence of a conjugated system, while compound 1 is the least stable.
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