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Two moles of an ideal gas are compressed at 300 K from a pressure of 1 atm to a pressure of 2 atm. The change in free energy is
  • a)
    1.46 KJ-mol⁻1
  • b)
    3.46 KJ-mol⁻1
  • c)
    5.46 KJ-mol⁻1
  • d)
    7.46 KJ-mol⁻1
Correct answer is 'B'. Can you explain this answer?
Most Upvoted Answer
Two moles of an ideal gas are compressed at 300 K from a pressure of 1...
Change in Free Energy Formula:

The change in free energy (∆G) of a system can be calculated using the equation:

∆G = ∆H - T∆S

Where:
∆G = Change in Free Energy
∆H = Change in Enthalpy
T = Temperature in Kelvin
∆S = Change in Entropy

Given Information:

Number of moles of gas (n) = 2
Initial pressure (Pi) = 1 atm
Final pressure (Pf) = 2 atm
Initial temperature (Ti) = 300 K

Step 1: Calculate the Change in Enthalpy (∆H)

Since the gas is an ideal gas, we can use the ideal gas equation to determine the change in enthalpy:

∆H = nR∆T

Where:
R = Gas constant (8.314 J/mol·K)
∆T = Change in temperature (Tf - Ti)

Since the temperature is constant in this case, ∆T = 0. Therefore, the change in enthalpy (∆H) is equal to zero.

Step 2: Calculate the Change in Entropy (∆S)

The change in entropy can be calculated using the equation:

∆S = nRln(Pf/Pi)

Where:
ln = Natural logarithm

Plugging in the values:

∆S = (2 moles)(8.314 J/mol·K)ln(2 atm/1 atm)
∆S = 2(8.314 J/mol·K)ln(2)
∆S ≈ 2(8.314 J/mol·K)(0.6931)
∆S ≈ 11.57 J/mol·K

Step 3: Calculate the Change in Free Energy (∆G)

Using the equation:

∆G = ∆H - T∆S

Plugging in the values:

∆G = 0 - (300 K)(11.57 J/mol·K)
∆G = -3471 J/mol

Converting to kilojoules:

∆G ≈ -3.47 kJ/mol

Answer:

The change in free energy (∆G) is approximately -3.47 kJ/mol.
Free Test
Community Answer
Two moles of an ideal gas are compressed at 300 K from a pressure of 1...
Free energy change =2.303×2×8.314×300log(2/1)
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