Why specific heat of Li in alkali metals is highest?
Specific Heat of Li in Alkali Metals:
Introduction:
The specific heat of a substance is the amount of heat energy required to raise the temperature of a unit mass of the substance by one degree Celsius. In the case of alkali metals, lithium (Li) has the highest specific heat compared to other alkali metals such as sodium (Na), potassium (K), rubidium (Rb), and cesium (Cs). This can be attributed to several factors.
Atomic Structure:
- Lithium has the smallest atomic size among the alkali metals. This results in a greater degree of electron-electron repulsion, leading to a higher energy requirement for temperature increase.
- The valence electrons in lithium are more tightly bound to the nucleus than in other alkali metals. This increased binding energy requires more heat energy to raise the temperature.
Electron Configuration:
- Lithium has a unique electron configuration compared to other alkali metals. It has two electrons in its inner shell and one valence electron in the outermost shell.
- Due to the presence of a single valence electron, lithium exhibits a higher degree of electron-electron repulsion. This repulsion necessitates more heat energy to increase the temperature.
Interatomic Forces:
- The strength of interatomic forces determines how tightly the atoms are held together in a substance. In lithium, the interatomic forces are relatively stronger compared to other alkali metals.
- These stronger interatomic forces require more heat energy to overcome, resulting in a higher specific heat.
Conclusion:
In summary, the specific heat of lithium in alkali metals is highest due to its atomic structure, electron configuration, and the strength of interatomic forces. Its smaller atomic size, increased electron-electron repulsion, and stronger interatomic forces contribute to the higher energy requirement for temperature increase. Understanding the specific heat of alkali metals, including lithium, is crucial for various scientific and technological applications.
Why specific heat of Li in alkali metals is highest?
They have low densities (lithium, sodium and potassium will float on water)
To make sure you are not studying endlessly, EduRev has designed NEET study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in NEET.