Resonance energy of benzene?
The resonance energy of benzene is 36 kcal/mol.
Benzene is commonly seen in Organic Chemistry and it has a resonance form. Benzene has two resonance structures, showing the placements of the bonds. Another example of resonance is ozone. Ozone is represented by two different Lewis structures. The difference between the two structures is the location of double bond.
This question is part of UPSC exam. View all NEET courses
Resonance energy of benzene?
Resonance Energy of Benzene
Benzene, with the chemical formula C6H6, is an aromatic hydrocarbon known for its unique structure and stability. It consists of a hexagonal ring of carbon atoms, with alternating double and single bonds. The resonance energy of benzene refers to the extra stability that benzene gains from the delocalization of its π-electrons.
Resonance in Benzene:
- In a simplified Lewis structure, benzene can be represented with three double bonds and three single bonds. However, this structure does not fully explain the stability and reactivity of benzene.
- The resonance structure of benzene is best described using a hybrid of the two limiting structures: a hexagonal ring with alternating single and double bonds. This delocalization of electrons creates a more stable molecule.
Delocalization of π-electrons:
- In benzene, the π-electrons are not localized between specific carbon atoms in double bonds, but rather spread out over the entire ring. This delocalization leads to a more even distribution of electron density and contributes to the stability of benzene.
- The delocalization of π-electrons in benzene is a result of the overlap of p-orbitals on adjacent carbon atoms. This overlap creates a continuous ring of π-electrons that can freely move within the ring.
Resonance Energy:
- The resonance energy of benzene refers to the extra stability gained by the delocalization of π-electrons. It is the difference in energy between the actual structure of benzene (with delocalized π-electrons) and the hypothetical structure with localized π-electrons.
- The resonance energy of benzene is estimated to be around 150 kJ/mol. This value indicates the stability provided by the delocalization of π-electrons.
- The resonance energy of benzene is significantly higher than that of other unsaturated hydrocarbons, such as cyclohexene or cyclohexadiene, which have localized π-electrons. This difference in stability is one of the reasons why benzene behaves differently in various chemical reactions.
Significance of Resonance Energy:
- The high resonance energy of benzene is responsible for its unique properties, such as its resistance to addition reactions and its tendency to undergo substitution reactions.
- The delocalization of π-electrons in benzene also contributes to its planar structure, as the continuous ring of electrons prefers to be in the same plane.
- Understanding the resonance energy of benzene is crucial in explaining the behavior of aromatic compounds and their reactivity in various chemical reactions.
In conclusion, the resonance energy of benzene is the extra stability gained from the delocalization of π-electrons in its structure. This delocalization creates a more stable molecule, and the resonance energy of benzene is significantly higher than that of other unsaturated hydrocarbons. The understanding of resonance energy is essential in explaining the unique properties and reactivity of benzene and other aromatic compounds.
To make sure you are not studying endlessly, EduRev has designed NEET study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in NEET.