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All questions of Stoichiometry for EmSAT Achieve Exam

What volume of 5 M Na2SO4 must be added to 25 mL of 1 M BaCl2 to produce 10 g of BaSO4?
  • a)
    8.58 mL
  • b)
    7.2 mL
  • c)
    10 mL
  • d)
    12 mL
Correct answer is option 'A'. Can you explain this answer?

Anjali Sharma answered
Na2SO4 + BaCI2 → BaSO4 + 2NaCl
No. of moles of BaSO4 = w/M = 10/233 = 0.0429
∴ No. of moles of Na2SO4 needed = M x V/1000
Or 0.0429 = 5 x V/1000
V = 8.58 mL

If 40 g of CaCO3 is treated with 40 g of HCl, which of the reactants will act as limiting reagent?
  • a)
    CaCO3
  • b)
    HCl
  • c)
    Both are equal
  • d)
    Cannot be calculated
Correct answer is option 'A'. Can you explain this answer?

Suresh Iyer answered

100 g of CaCO3 reacts with 73 g of HCl
40 g of CaCO3 will react with 73/100 x 40 = 29.2 g of HCl
Since CaCO3 is completely consumed and some amount (40 - 29.2 = 10.8g) of HCl remains unreacted and hence, CaCO3 is limiting reagent.

How much copper is present in 50 g of CuSO4?
  • a)
    19.90 g
  • b)
    39.81 g
  • c)
    63.5 g
  • d)
    31.71 g
Correct answer is option 'A'. Can you explain this answer?

Preeti Iyer answered
Molar mass of CuSO4 = 63.5 + 32 + 4 x 16 = 159.5 g
Mass of copper present in 159.5 g of CuSO4 = 63.5 g
∴ Mass of copper present in 50 g of CuSO4

The final molarity of a solution made by mixing 50 mL of 0.5 M HCl, 150 mL of 0.25 M HCl and water to make the volume 250 mL is
  • a)
    0.5 M
  • b)
    1 M
  • c)
    0.75 M
  • d)
    0.25 M
Correct answer is option 'D'. Can you explain this answer?

Swara Dey answered
To find the final molarity of the solution, we need to consider the principle of conservation of moles. This principle states that the total number of moles of solute before and after mixing should remain the same.

- Initial moles of HCl in 50 mL of 0.5 M HCl:
Moles = Molarity x Volume
Moles = 0.5 M x 0.050 L = 0.025 moles

- Initial moles of HCl in 150 mL of 0.25 M HCl:
Moles = Molarity x Volume
Moles = 0.25 M x 0.150 L = 0.0375 moles

- Total moles of HCl before mixing:
Total moles = 0.025 moles + 0.0375 moles = 0.0625 moles

- Final volume of the solution = 250 mL = 0.250 L

- Final molarity of the solution:
Molarity = Total moles / Final volume
Molarity = 0.0625 moles / 0.250 L = 0.25 M

Therefore, the final molarity of the solution is 0.25 M.

The weight of AgCl precipitated when a solution containing 5.85 g of NaCl is added to a solution containing 3.4 g of AgNO3 is
  • a)
    28 g
  • b)
    9.25 g
  • c)
    2.870 g
  • d)
    58 g
Correct answer is option 'C'. Can you explain this answer?

Dev Patel answered
AgNO3 + NaCl → AgCl + NaNO3
No. of moles of AgNO3 = 3.4/170 = 0.02
No, of moles of NaCl = 5.85/58.5 = 0.1
Limiting reagent = AgNO3
1 mole of AgNO3 produces 1 mole of AgCl
0.02 mole of AgNO3 will produce 0.02 mole of AgCl
Weight of AgCl produced = 0.02 x 143.5 = 2.870 g.

What is the mass percent of oxygen in ethanol?
  • a)
    52.14%
  • b)
    13.13%
  • c)
    16%
  • d)
    34.73%
Correct answer is option 'D'. Can you explain this answer?

Dev Patel answered
Molecular formula of ethanol = C2H5OH
Molar mass of ethanol of 2 x 12.01 + 6 x 1.008 + 16 = 46.068g
Mass percent of oxygen = 16/46.068 x 100 = 34.73%

How much mass of sodium acetate is required to make 250 mL of 0.575 molar aqueous solution?
  • a)
    11.79 g
  • b)
    15.38 g
  • c)
    10.81 g
  • d)
    25.35 g
Correct answer is option 'A'. Can you explain this answer?

Saanvi Nair answered
To calculate the mass of sodium acetate required to make a 0.575 M aqueous solution, we can use the formula:

Molarity (M) = moles of solute / volume of solution in liters

First, we need to convert the volume of the solution from milliliters to liters:

250 mL = 250/1000 = 0.25 L

Next, we rearrange the formula to solve for moles of solute:

moles of solute = Molarity (M) x volume of solution in liters

Given that the molarity is 0.575 M and the volume is 0.25 L, we can substitute these values into the formula:

moles of solute = 0.575 M x 0.25 L = 0.14375 moles

The molar mass of sodium acetate (NaC2H3O2) is calculated as follows:

Na: 1 atom x 22.99 g/mol = 22.99 g/mol
C: 2 atoms x 12.01 g/mol = 24.02 g/mol
H: 3 atoms x 1.01 g/mol = 3.03 g/mol
O: 2 atoms x 16.00 g/mol = 32.00 g/mol

Total molar mass = 22.99 + 24.02 + 3.03 + 32.00 = 82.04 g/mol

Finally, we can calculate the mass of sodium acetate required using the moles of solute and the molar mass:

mass of sodium acetate = moles of solute x molar mass
mass of sodium acetate = 0.14375 moles x 82.04 g/mol = 11.79 g

Therefore, the correct answer is option A) 11.79 g.

2.82 g of glucose is dissolved in 30 g of water. The mole fraction of glucose in the solution is
  • a)
    0.01
  • b)
    0.99
  • c)
    0.52
  • d)
    1.66
Correct answer is option 'A'. Can you explain this answer?

Mira Joshi answered
No. of moles of glucose = 2.82/180 = 0.01567
No. of moles of water = 30/18 = 1.667
Total no. of moles of solution = 0.01567 + 1.667 = 1.683
Mole fraction of glucose = 0.01567/1.683 = 0.0093 = 0.01

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