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All questions of P-block elements for NEET Exam

The correct statements among the given are 
  • a)
    Antimony belongs to 15th group and 5th period
  • b)
    electron gain enthalpy of P > N > S > O
  • c)
    Minimum and maximum oxidation number of phosphorus is -3 and +6
  • d)
    Fluoroapatite, formula is Ca6(PO4)6 CaF2
Correct answer is option 'A'. Can you explain this answer?

Divey Sethi answered
Option A: Group 5A (or VA) of the periodic table are the pnictogens:  the nonmetals nitrogen (N), and phosphorus (P), the metalloids arsenic (As) and antimony (Sb), and the metal bismuth (Bi).
Option B: The electron gain enthalpy of P< N< S< O.
Option C: Minimum and maximum oxidation number of phosphorus are -3 and +5 respectively.
Option D: Fluorapatite is a phosphate mineral with the formula Ca5(PO4)3F .
Hence, option A is correct.

 
    Correct answer is '4'. Can you explain this answer?

    Molecular Orbital Theory and Antibonding Orbitals in Nitrogen

    Molecular orbital theory (MOT) is a theoretical model that describes the behavior of electrons in molecules based on the principles of quantum mechanics. It is used to explain and predict the properties of molecules, including their electronic and magnetic properties, bond lengths, bond angles, and so on.

    In MOT, the electrons in a molecule are treated as waves that are described by molecular orbitals (MOs), which are mathematical functions that represent the probability of finding an electron at a given point in space. These MOs are formed by combining the atomic orbitals of the atoms in the molecule.

    Antibonding orbitals are MOs that have a higher energy than the atomic orbitals from which they are formed. When electrons occupy these orbitals, they weaken the bond between the atoms in the molecule, making it more likely to break apart.

    Nitrogen has five valence electrons, which are represented by the atomic orbitals s and p. In the molecule N2, these atomic orbitals combine to form five MOs: two bonding MOs, two antibonding MOs, and one nonbonding MO.

    The two bonding MOs are lower in energy than the atomic orbitals from which they are formed, and they help to hold the two nitrogen atoms together. The nonbonding MO is filled with two electrons, which are shared equally between the two nitrogen atoms and do not contribute to the bond strength.

    The two antibonding MOs are higher in energy than the atomic orbitals from which they are formed, and they weaken the bond between the two nitrogen atoms. When all five valence electrons are placed into the MOs, there are four electrons in the antibonding MOs and one electron in the nonbonding MO.

    Therefore, according to molecular orbital theory, there are four electrons present in the antibonding orbitals of nitrogen.

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'B'. Can you explain this answer?

    Nikita Singh answered
    The second ionization energy refers to the energy required to remove the electron from the corresponding monovalent cation of the respective atom.
    It is expected to increase from left to right in the periodic table with the decrease in atomic size.
    Since the Oxygen atom gets a stable electronic configuration, 2s22p3 after removing one electron, the O+ shows greater ionization energy than F+ as well as N+
    Thus, correct order will be: O > F > N > C

     In the third period of the periodic table the element having smallest size is        
    • a)
      Na
    • b)
      CI
    • c)
      Ar
    • d)
      Si
    Correct answer is option 'B'. Can you explain this answer?

    Aarav Sharma answered
    The third period contains eight elements: sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon.
    In a period from left to right atomic size decreases due to Increase in nuclear charge.
    but the noble gases are bigger than the halogens as they have octet and sort of repulsion occurs in the shells.
    so the smallest element in a period is the halogen.so chlorine Cl is the smallest.

    A brown ring is formed in the ring test for NO3 ion. It is due to the formation of
    • a)
      [Fe(H2O)5 (NO)]2+
    • b)
       FeSO4.NO2
    • c)
      [Fe(H2O)4(NO)2]2+
    • d)
      FeSO4.HNO3
    Correct answer is option 'A'. Can you explain this answer?

    Sushil Kumar answered
    When freshly prepared solution of FeSOis added in a solution containing NO3– ion, it leads to formation of a brown coloured complex. This is known as brown ring test of nitrate.

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'A'. Can you explain this answer?

    (i) Nitrogen is a non-metal.
    (ii) Phosphorus is a non-metal.
    (iii) Arsenic is a metalloid and shows Sublimation.
    (iv) Bismuth is metal and shows the Inert pair effect.
    Hence, option A is correct.

    Which of the following is a polar molecule ? [NEET 2013]
    • a)
      SF4
    • b)
      SiF4
    • c)
      XeF4
    • d)
      BF3
    Correct answer is option 'A'. Can you explain this answer?

    Rajesh Datta answered
    SF4 has 4 bond pairs and 1 lone pair of electrons, sp3d hybridisation leads to irregular shapeand resultant
    μ ≠ 0.

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'B'. Can you explain this answer?

    Gauri Datta answered
    Oxidation of ammonia with CuO produces nitrogen gas and water vapor. This reaction is represented as:

    2NH3 + 3CuO → 3Cu + N2 + 3H2O

    The gaseous chemical produced in this reaction is nitrogen gas (N2), which is also obtained by reacting excess ammonia with chlorine. This reaction is represented as:

    2NH3 + Cl2 → N2 + 2HCl

    Explanation:

    - Ammonium nitrate: Heating ammonium nitrate results in the decomposition of ammonium nitrate into nitrogen gas, water vapor, and oxygen gas. The reaction is represented as:

    NH4NO3 → N2 + 2H2O + O2

    - Potassium dichromate: Heating potassium dichromate results in the production of oxygen gas and potassium chromate. The reaction is represented as:

    4K2Cr2O7 → 4K2CrO4 + 3O2

    - Catalytic oxidation of ammonia: Catalytic oxidation of ammonia involves the use of a catalyst (such as platinum or palladium) to oxidize ammonia to nitrogen gas and water vapor. The reaction is represented as:

    4NH3 + 5O2 → 4NO + 6H2O
    2NO + O2 → 2NO2
    4NO2 + O2 → 2N2O5
    N2O5 → N2 + 2.5O2

    - Reacting excess ammonia with chlorine: This reaction involves the reaction of excess ammonia with chlorine gas to produce nitrogen gas and hydrochloric acid. The reaction is represented as:

    2NH3 + Cl2 → N2 + 2HCl

    Therefore, option B, reacting excess ammonia with chlorine, is the correct answer.

    Which of the following molecular species has unpaired electron(s) ?
    • a)
      N2
    • b)
      O2
    • c)
      NO+
    • d)
      CN-
    Correct answer is option 'B'. Can you explain this answer?

    Priya Chavan answered
     contains two unpaired electrons and is paramagnetic in nature. On the other hand,  and  contains all paired electrons and are diamagnetic in nature. 

    Direction (Q. Nos. 8-12) This section contains 5 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONE or MORE THAN ONE are correct.
    Q. 
    Which of the following can act as dehydrating agent ?
    • a)
      P4O10
    • b)
      POCI3
    • c)
      Cone.H2SO4
    • d)
      P4O6 
    Correct answer is option 'A,B,C'. Can you explain this answer?

    Raksha Nambiar answered
    Dehydrating agents are substances that have the ability to remove water from other substances. They are commonly used in chemical reactions where the removal of water is necessary. In the given options, the substances that can act as dehydrating agents are:

    a) P4O10 (Phosphorus pentoxide):
    - Phosphorus pentoxide is a powerful dehydrating agent.
    - It reacts vigorously with water to form phosphoric acid, removing water from the system.
    - The chemical reaction is as follows: P4O10 + 6H2O → 4H3PO4

    b) POCI3 (Phosphorus trichloride):
    - Phosphorus trichloride is also a dehydrating agent.
    - It reacts with water to form phosphorous acid, removing water from the system.
    - The chemical reaction is as follows: POCI3 + 3H2O → H3PO3 + 3HCl

    c) Cone.H2SO4 (Concentrated sulfuric acid):
    - Concentrated sulfuric acid is a highly effective dehydrating agent.
    - It has a strong affinity for water and can remove water molecules from other substances.
    - Sulfuric acid reacts with water to release a large amount of heat, which is an indication of its dehydrating properties.

    d) P4O6 (Phosphorus trioxide):
    - Phosphorus trioxide is not a dehydrating agent.
    - It is a reducing agent and reacts with water to form phosphorous acid (H3PO3), not removing water from the system.

    Therefore, the correct options are a) P4O10, b) POCI3, and c) Cone.H2SO4, as they can act as dehydrating agents by removing water from other substances.

    Among the following which is the strongest oxidising agent? [2009]
    • a)
      Br2
    • b)
      I2
    • c)
      Cl2
    • d)
      F2
    Correct answer is option 'D'. Can you explain this answer?

    Rajesh Datta answered
    Standard reduction potential of halogens are positive and decreases from fluorine to iodine. Therefore halogens act as strong oxidising agent and their oxidising power decreases from fluorine to iodine.

    Which of the following is the strongest Lewis base?
    • a)
      NBr3
    • b)
      NF3
    • c)
      NCl3
    • d)
      NI3
    Correct answer is option 'D'. Can you explain this answer?

    Correct Answer :- D
    • Lewis bases need to be able to donate electrons. Fluorine is the most electronegative element in the halogens followed by chlorine, bromine and iodine. 
    • Due to fluorine being strongly electronegative, it draws the electron density towards itself which makes it difficult for nitrogen atom to donate its lone pair of electrons. So, NF is the least basic. This trend follows the strength of electronegativity of the halides. 
    • Since iodine is least electronegative, it is the most basic trihalide of nitrogen.
    So, we have the trend, in decreasing order of basic strength:
    NF3 < NCl3 < NBr3 < NI3

    At what temperature white phosphorous changes to red phosphorous?
    • a)
      300° C
    • b)
      450° C
    • c)
      50° C
    • d)
      400° C
    Correct answer is option 'A'. Can you explain this answer?

    Ananya Singh answered
    According to NCERT, red phosphorus is obtained by heating white phosphorus at 573 K in an inert atmosphere for several days. In degree celius, temperature = 300⁰ C (573K - 273).

    Which are correct statements ? 
    • a)
      The melting point of antimony is higher than bismuth
    • b)
      Ionisation energy of C < O < N
    • c)
      In 15th group, all show allotropy except bismuth and nitrogen
    • d)
      Maximum covalency of nitrogen and Phosphorus are 4 and 5 respectively 
    Correct answer is option 'A,B,C,D'. Can you explain this answer?

    Om Desai answered
    Option A: Bismuth has 6 electron shells, whereas Antimony has 5 electron shells. Because of this, the attractive force between two Bismuth atoms is less due to electron shielding, resulting in bismuth possessing a lower boiling point than antimony.
    Option B: In a period of moving from left to right, the ionization energy increases. Since N has a table half-filled 2p subshell which requires large energy.
    Thus, the correct order of ionization energy is C < O < N.
    Option C: Except N and Bi, all the group 15 elements exhibits allotropy. The allotropes of phosphorous are rather complex but essentially, there are three allotropic forms known as white, red, and black phosphorous.
    Option D: Maximum covalency of N & P are 4 and 5.
    Hence, option A,B,C,D is correct.

    Which of the following is not a use of noble gases?
    • a)
      Argon is widely used for filling incandescent electric bulbs
    • b)
      Neon is used in safety devices for protecting electrical instruments
    • c)
      Radon is used in radiotherapy of cancer
    • d)
      Helium is filled in tubes of cycles and scooters tyres
    Correct answer is option 'D'. Can you explain this answer?

    Helium is filled in tubes of cycles and scooters tyres
    Helium is not used for filling tubes of cycles and scooters tyres. It is primarily used in other applications such as:

    Argon:
    - Widely used for filling incandescent electric bulbs to prevent the filament from oxidizing.
    - Used in welding and metal fabrication to shield the weld area from atmospheric gases.

    Neon:
    - Used in safety devices for protecting electrical instruments due to its ability to produce a bright light when an electric current passes through it.
    - Also commonly used in neon signs for advertising.

    Radon:
    - Used in radiotherapy of cancer as a radiation source to destroy cancer cells.
    - It can also be used in some geological research applications to trace the movement of underground gases.
    In contrast, helium is typically used in applications such as:
    - Cryogenics to achieve low temperatures
    - In filling balloons for various purposes
    - In cooling nuclear reactors and MRI machines
    Therefore, while noble gases have a variety of important uses, filling tubes of cycles and scooters tyres with helium is not one of them.

      is the structure of
    • a)
      Phosphorous acid
    • b)
      Hypophosphorus Acid
    • c)
      Phosphoric acid
    • d)
      Pyrophosphoric acid
    Correct answer is option 'B'. Can you explain this answer?

    Baby Ghosh answered
    Of course..this is a structure of hypo phosphorus acid. It is a mineral acid with formula H4P2O6.In hypophosphorus acid,the phosphorus bonds are identical and joined with p-p bond .there is also joined oxygen and hydrogen bonds as the structure follows.

    Most metal oxides are
    • a)
      Covalent in nature
    • b)
      Acidic in nature
    • c)
      Basic in nature
    • d)
      None of these
    Correct answer is option 'C'. Can you explain this answer?

    Rashi Bose answered
    Most metal oxides are ionic crystals with high melting and boiling points. They are compounds that contain at least one metal and one oxygen atom, and are generally basic in nature. Metal oxides are basic because they react with acids to form salt and water, neutralizing the acids. 

    Which one of the following  arrangements does not give the correct picture of the trends indicated against it ? [2008]
    • a)
      F2 > Cl2 > Br2 > I2 : Oxidizing power
    • b)
      F2 > Cl2 > Br2 > I2 : Electron gain enthalpy
    • c)
      F2 > Cl2 > Br2 > I2 : Bond dissociation energy
    • d)
      F2 > Cl2 > Br2 > I2 : Electronegativity.
    Correct answer is option 'B,C'. Can you explain this answer?

    Nisha Pillai answered
    From the given options we find option (a) is correct. The oxidising power of halogens follow the order F2 > Cl2 > Br2 > I2 . Option (b) is incorrect because it in not the correct order of electron gain enthalpy of halogens. The correct order is Cl2 > F2 > Br2 > I2 . The low value of F2 than Cl2 is due to its small size. Option (c) is incorrect. The correct order of bond dissociation energies of halogens is Cl2 > Br2 > F2 > I2 . Option (d) is correct. It is the correct order of electronegativity values of halogens. Thus option (b) and (c) are incorrect.

    Which is the correct order of basic strength ?
    • a)
       NH2OH < N2H4 < NH3
    • b)
       N2H4 <  NH2OH < NH3
    • c)
       NH3 < N2H4 < NH2OH
    • d)
       NH2OH < NH3 < N2H4
    Correct answer is option 'A'. Can you explain this answer?

    Ashish Nambiar answered
    NH2OH and NH2—NH2 may be considered as NH3 derivatives in which H is replaced but — OH and NH2 respectively. Due to their electron withdrawing nature, these groups decreases electron density over nitrogen making them less basic. The effect of — OH group is stronger than —NH2

    Which of the following statements is not correct?
    • a)
      Helium has the lowest boiling point among the noble gases
    • b)
      Argon is used in electric bulbs
    • c)
      Krypton is obtained during radioactive disintegration
    • d)
      Xe forms XeF6
    Correct answer is option 'C'. Can you explain this answer?

    Jyoti Sengupta answered
    Air is also the most important source for the other noble gases.T races of krypton are found in various minerals, the most important source of Krypton is Earth's atmosphere. Helium obtained from natural gas and radon is obtained as a byproduct during radioactive disintegration.
    So Rn is obtained during radioactive disintegration not Kr.
    So Krypton is obtained during radioactive disintegration is the wrong statement.

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