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What does the negative electronic energy (En) for hydrogen atom mean?
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What does the negative electronic energy (En) for hydrogen atom mean?
The energy of the electron in a hydrogen atom has a negative sign for all possible orbits


This negative sign means that the energy of the electron in the atom is lower than energy of a free electron at rest. A free electron at rest is an electron that is infinitely far away from the nucleus and is assigned the energy value of zero. Mathematically, this corresponds to setting n equal to infinity in the equation so that E infinity= 0. As the electron gets closer to the nucleus (as n decreases), E n becomes larger in absolute value and more and more negative. The most negative energy value is given by n=1 which corresponds to the most stable orbital. And We call this the Ground State .
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What does the negative electronic energy (En) for hydrogen atom mean?
What does the negative electronic energy (En) for hydrogen atom mean?

The negative electronic energy (En) for a hydrogen atom refers to the amount of energy required to remove an electron from the hydrogen atom and place it at a distance infinitely far away from the atom. It is a measure of the stability of the atom and is directly related to the behavior of the electron within the atom.

Understanding the concept of electronic energy

- The electronic energy of an atom arises due to the interaction between the positively charged nucleus and the negatively charged electron(s).
- In the case of a hydrogen atom, which consists of a single electron orbiting a single proton, the electronic energy is determined by the electrostatic attraction between the electron and the proton.

The significance of negative electronic energy

- The negative sign of the electronic energy indicates that energy is released when an electron is bound to the hydrogen atom. This implies that the electron is in a lower energy state when it is in the atom compared to when it is infinitely far away.
- The negative electronic energy is a result of the attractive force between the electron and the proton, which allows the electron to be confined to a specific energy level within the atom.
- This negative energy is responsible for holding the electron in its orbit around the nucleus, preventing it from escaping and causing the atom to be stable.

Quantization of energy levels

- The electronic energy of the hydrogen atom is quantized, meaning it can only exist in certain discrete energy levels.
- Each energy level is associated with a specific value of negative electronic energy, denoted as En, where n is an integer representing the energy level.
- The energy levels are numbered as n=1, n=2, n=3, and so on, with n=1 being the ground state and higher values of n corresponding to higher energy levels.

Conclusion

In conclusion, the negative electronic energy for a hydrogen atom signifies the stability of the atom and the energy released when the electron is bound to the nucleus. The negative sign indicates that the electron is in a lower energy state within the atom compared to when it is infinitely far away. The quantization of energy levels in the hydrogen atom further demonstrates the discrete nature of electronic energy and the specific values associated with each energy level.
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What does the negative electronic energy (En) for hydrogen atom mean?
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