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If 60% of a first order reaction was completed in 60 minutes, 50% of the same reaction would be completed in aproximately [2007]
  • a)
    45 minutes
  • b)
    60 minutes
  • c)
    40 minutes
  • d)
    50 minutes (log 4 = 0.60, log 5 = 0.69)
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
If 60% of a first order reaction was completed in 60 minutes, 50% of t...
For a first order reaction
when t = 60 and x = 60%
Now,
 =  45.31 min.
View all questions of this test
Most Upvoted Answer
If 60% of a first order reaction was completed in 60 minutes, 50% of t...
Given:
- First-order reaction
- 60% of the reaction completed in 60 minutes

To find:
- The time required for 50% of the same reaction to be completed

Explanation:
A first-order reaction follows the rate law equation: Rate = k[A], where [A] represents the concentration of the reactant and k is the rate constant.

Using the formula:
The integrated form of the first-order rate law equation is given by the equation: ln[A]t = -kt + ln[A]0, where [A]t is the concentration of the reactant at time t and [A]0 is the initial concentration.

Given:
- 60% of the reaction completed in 60 minutes
- We can assume the initial concentration ([A]0) to be 100% or 1

Calculating:
Using the given information, we know that when 60% of the reaction is completed, the concentration of the reactant is reduced to 40% or 0.4.

So, plugging in the values into the integrated form of the rate law equation, we get:
ln(0.4) = -k * 60 + ln(1)

Simplifying the equation:
-0.916 = -60k

Solving for k:
k = 0.01527 min^-1

Using the formula:
Now, we need to find the time required for 50% of the reaction to be completed. Let's assume this time as t.

Using the integrated form of the rate law equation again, we get:
ln(0.5) = -0.01527 * t + ln(1)

Simplifying the equation:
-0.6931 = -0.01527 * t

Solving for t:
t = 45.37 minutes

Conclusion:
Therefore, approximately 50% of the same reaction would be completed in approximately 45 minutes. The correct answer is option A.
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If 60% of a first order reaction was completed in 60 minutes, 50% of the same reaction would be completed in aproximately [2007]a)45 minutesb)60 minutesc)40 minutesd)50 minutes (log 4 = 0.60, log 5 = 0.69)Correct answer is option 'A'. Can you explain this answer?
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