Which of the following statement about fluorine is not correct?a)Elect...
Industrial production of fluorine entails the electrolysis of hydrogen fluoride in the presence of potassium fluoride. Under these conditions, the potassium fluoride (KF) converts to potassium bifluoride (KHF2), which is the actual electrolyte. This potassium bifluoride aids electrolysis by greatly increasing the electrical conductivity of the solution. Fluorine gas forms at the anode, and hydrogen gas at the cathode.
HF + KF → KHF2
2 KHF2 → 2 KF + H2 + F2
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Which of the following statement about fluorine is not correct?a)Elect...
Fluorine Preparation:
Fluorine can indeed be prepared by the electrolysis of fused metal fluorides. This process involves passing an electric current through a molten metal fluoride, typically potassium fluoride, to produce fluorine gas. This method is widely used for industrial production of fluorine.
Incorrect Statement:
The statement "Fluorine cannot be prepared by electrolysis of fused metal fluorides" is incorrect. As mentioned above, fluorine can be successfully obtained through this electrolysis process. Therefore, option C is not correct in relation to fluorine properties.
Other Statements:
a) The electron affinity of chlorine is greater than that of fluorine: This statement is correct, as chlorine has a higher electron affinity compared to fluorine. This means that chlorine has a greater tendency to accept an electron to form an anion.
b) The bond energy of fluorine is less than that of chlorine: This statement is also accurate. Fluorine has a stronger bond energy compared to chlorine, due to its smaller atomic size and higher electronegativity.
d) Fluorine does not form oxoacid: This statement is incorrect. Fluorine is known to form oxoacids, such as hypofluorous acid (HOF) and fluorosulfuric acid (HSO3F), among others.
In conclusion, the incorrect statement regarding fluorine is that it cannot be prepared by the electrolysis of fused metal fluorides.
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