Ethyl isocyanide on acidic hydrolysis generatesa)Ethylamine salt and m...
(a) : Alkyl isocyanides are hydrolysed by dilute mineral acids to form primary amines.Read more on Sarthaks.com - https://www.sarthaks.com/44040/ethyl-isocyanide-on-hydrolysis-in-acidic-medium-generates
View all questions of this test
Ethyl isocyanide on acidic hydrolysis generatesa)Ethylamine salt and m...
Acidic hydrolysis of ethyl isocyanide results in the formation of ethylamine salt and methanoic acid. Here's a detailed explanation of the process:
1. Definition of Ethyl Isocyanide:
- Ethyl isocyanide is an organic compound with the chemical formula C2H5NC. It consists of an ethyl group (C2H5) attached to a nitrogen atom (N) with a triple bond to a carbon atom (C).
2. Acidic Hydrolysis:
- Acidic hydrolysis is a chemical reaction in which a compound reacts with water under acidic conditions to produce two or more products.
- In the case of ethyl isocyanide, when it undergoes acidic hydrolysis, it reacts with water (H2O) in the presence of an acid catalyst.
3. Reaction Mechanism:
- The acidic hydrolysis of ethyl isocyanide proceeds through a nucleophilic attack by water on the isocyanide carbon atom.
- The nitrogen atom in ethyl isocyanide is relatively electron deficient due to the presence of the triple bond, making it susceptible to attack by nucleophiles.
- The water molecule acts as a nucleophile and attacks the carbon atom, breaking the triple bond and forming a new bond with the carbon atom.
- Simultaneously, the nitrogen atom forms a bond with a hydrogen ion (H+) from the acid catalyst to maintain its positive charge.
- As a result, the ethyl group is released as an ethylamine cation (C2H5NH3+) and the carbon atom is now bonded to an oxygen atom from the water molecule.
4. Products of Acidic Hydrolysis:
- The products of acidic hydrolysis of ethyl isocyanide are ethylamine salt and methanoic acid.
- The ethylamine cation (C2H5NH3+) combines with an anion (negative ion) from the acid catalyst, such as chloride (Cl-) or acetate (CH3COO-), to form the ethylamine salt.
- The carbon atom, now bonded to an oxygen atom, forms a carboxylic acid functional group, specifically methanoic acid (HCOOH), also known as formic acid.
Therefore, the correct answer is option 'A': Ethylamine salt and methanoic acid.
To make sure you are not studying endlessly, EduRev has designed NEET study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in NEET.