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Solubility of the alkaline earth‘s metal sulphates in water decreases in the sequence :
  • a)
    Ba > Mg > Sr > Ca
  • b)
    Mg > Ca > Sr > Ba
  • c)
    Ca > Sr > Ba > Mg
  • d)
    Sr > Ca > Mg > Ba
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
Solubility of the alkaline earth‘s metal sulphates in water decr...
Mg > Ca > Sr > Ba.
The solubility of sulphate decreases on moving down the group. The values of solubility products
which decrease gradually also explain the decrease in solubility on moving down the group.
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Community Answer
Solubility of the alkaline earth‘s metal sulphates in water decr...
The solubility of the alkaline earth's metal sulphates in water decreases in the sequence Mg>Ca>Sr>Ba.

With the increase in the cationic size on moving down the group, the extent of the hydration of the cation decreases. However, the decrease in the lattice energy with increase in cationic size is small.

Thus, the decrease in hydration energy is more significant than the decrease in lattice energy. Hence, the solubility of the alkaline earth's metal sulphates in water decreases on moving down the group.
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Solubility of the alkaline earth‘s metal sulphates in water decreases in the sequence :a)Ba > Mg > Sr > Cab)Mg > Ca > Sr > Bac)Ca > Sr > Ba > Mgd)Sr > Ca > Mg > BaCorrect answer is option 'B'. Can you explain this answer?
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