Select the incorrect statement about the XeF6.a)It has capped octahedr...
Capped octahedron (or distorted octahedron)
In tetramer, four square pyramidal XeF5+ ions are joined to two similar ions by means of two bridging F- ions. The Xe-F distances are 1.84 A on the square pyramidal units and 2.23 A and 2.60 A in the bridging groups. The solid has various crystalline forms, of which three are tetrameric and a fourth has both hexamers and tetramers.
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Select the incorrect statement about the XeF6.a)It has capped octahedr...
Incorrect Statement: It has capped octahedron or distorted octahedral structure with one lone pair.
Explanation:
Xenon hexafluoride (XeF6) is an inorganic compound consisting of xenon and fluorine atoms. It is a powerful fluorinating agent and is commonly used in chemical reactions to introduce fluorine atoms into organic molecules.
XeF6 does not have a capped octahedron or distorted octahedral structure with one lone pair. Instead, it has an octahedral structure with no lone pairs. The central xenon atom is surrounded by six fluorine atoms, forming a regular octahedron. Each fluorine atom is bonded to the xenon atom through a single covalent bond, resulting in a total of six bonds.
The correct statement regarding the structure of XeF6 is that it has an octahedral structure with no lone pairs. This is important to note because the absence of lone pairs affects the reactivity and chemical behavior of XeF6.
Other Statements:
a) In various non-aqueous solvents, it forms a tetramer Xe4F24.
This statement is correct. XeF6 can undergo self-association in non-aqueous solvents, leading to the formation of a tetrameric species, Xe4F24. In this tetramer, four XeF6 molecules are connected through bridging fluorine atoms, resulting in a cluster with a total of 24 fluorine atoms.
b) Solid Xenon hexafluoride is polymorphic.
This statement is correct. XeF6 exhibits polymorphism, which means it can exist in different crystal structures. At low temperatures, XeF6 crystallizes in a monoclinic structure, while at higher temperatures, it transforms into a cubic structure. This ability to exist in multiple crystal structures is a characteristic feature of XeF6.
c) None of these.
This statement is incorrect as explained above.
In summary, the incorrect statement is that XeF6 has a capped octahedron or distorted octahedral structure with one lone pair. The correct statement is that XeF6 has an octahedral structure with no lone pairs.
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