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For the cell (at 298 K)
Ag(s) | AgCl(s) | Cl– (aq) || AgNO3 (aq) | Ag(s) 
Which of following is correct :
  • a)
    The cell e.m.f. will be zero when [Ag+]a = [Ag+]c ([Ag+] in anodic compartment = [Ag+] in cathodic compartment).
  • b)
    The amount of AgCl(s) precipitate in anodic compartment will decrease with the working of the cell.
  • c)
    The concentration of [Ag+] = constant, in anodic compartment during working of cell.
  • d)
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
For the cell (at 298 K)Ag(s) | AgCl(s) | Cl– (aq) || AgNO3 (aq) ...
It [Ag+]3 = [Ag+]c then both the electrodes have same potential. [AT+] will increase in anodic compartment. AgCI(s) precipitate in anodic compartment will increase. 
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For the cell (at 298 K)Ag(s) | AgCl(s) | Cl– (aq) || AgNO3 (aq) | Ag(s)Which of following is correct :a)The cell e.m.f. will be zero when [Ag+]a = [Ag+]c ([Ag+] in anodic compartment = [Ag+] in cathodiccompartment).b)The amount of AgCl(s) precipitate in anodic compartment will decrease with the working of the cell.c)The concentration of [Ag+] = constant, in anodic compartment during working of cell.d)Correct answer is option 'A'. Can you explain this answer?
Question Description
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