**Amines:**

Amines are organic compounds that contain a nitrogen atom bonded to one or more alkyl or aryl groups. They can be classified as primary (RNH2), secondary (R2NH), or tertiary (R3N) amines, depending on the number of alkyl or aryl groups attached to the nitrogen atom. Amines are known to exhibit basic properties.

**Alcohols:**

Alcohols are organic compounds that contain a hydroxyl (-OH) group attached to a carbon atom. They can be classified as primary (RCH2OH), secondary (R2CHOH), or tertiary (R3COH) alcohols, depending on the number of alkyl groups attached to the carbon atom. Alcohols can exhibit both acidic and basic properties, but they are generally weaker bases compared to amines.

**Basicity of Amines vs Alcohols:**

Amines are generally more basic than comparable alcohols due to the following reasons:

1. **Lone Pair of Electrons:** Amines have a lone pair of electrons on the nitrogen atom, which is available for donation. This lone pair can readily accept a proton (H+) from an acid, making amines good bases. In contrast, alcohols do not have a readily available lone pair of electrons for proton acceptance.

2. **Electronegativity Difference:** The electronegativity of nitrogen is lower than that of oxygen. This difference in electronegativity leads to a greater electron density on the nitrogen atom, making the lone pair of electrons more available for proton acceptance. In alcohols, the higher electronegativity of oxygen tends to attract electron density away from the oxygen atom, making the lone pair of electrons less available.

3. **Stability of Conjugate Acid:** The stability of the conjugate acid formed after accepting a proton also affects the basicity of a compound. Amines form stable ammonium ions, which have resonance stabilization due to the delocalization of the positive charge over the alkyl or aryl groups. This resonance stabilization enhances the basicity of amines. On the other hand, alcohols form alkoxide ions, which are less stable and do not experience resonance stabilization to the same extent.

4. **Inductive Effect:** The alkyl or aryl groups attached to the nitrogen atom in amines can exert an electron-donating inductive effect, which increases the electron density on the nitrogen atom. This increased electron density enhances the basicity of amines. In alcohols, the alkyl groups attached to the oxygen atom can also exert an inductive effect, but it is generally weaker compared to the effect of alkyl groups on nitrogen.

Overall, amines are more basic than comparable alcohols due to the presence of a lone pair of electrons on the nitrogen atom, the lower electronegativity of nitrogen compared to oxygen, the stability of the formed conjugate acid, and the electron-donating inductive effect of alkyl or aryl groups on nitrogen.