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Which of the following organometallic compound is σ and π bonds?
  • a)
    [Fe(η2-C₂H₅)₂]
  • b)
    [PtCl₃(η2-C₂H₄)]
  • c)
    [Co(CO)₅NH₃]2
  • d)
    Al(CH₃)₃
Correct answer is option 'C'. Can you explain this answer?
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[Co(CO)5NH3]+2 is sigma and pi bonded,in this organometallic compound,bond b/w Cobalt and CO ligands have both sigma and pi character.sigma bond formation b/w metal and carbon of CO takes place by overlap of filled bonding π2p of CO with an empty metal d-orbital.The 2nd overlap takes place b/w metal and d-orbital with an empty antibonding pi orbital of the CO resulting in additional π-bond b/w the metal and same CO molecule.
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Which of the following organometallic compound is σ and π bonds?a)[Fe(η2-CH)]b)[PtCl(η2-CH)]c)[Co(CO)NH]2d)Al(CH)Correct answer is option 'C'. Can you explain this answer?
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