The enthalpies of formation of HF and HCI are -161 KJ and -92 KJ respe...
More negative the value of enthalpy of formation, more is the stability. On account of this, HF is more stable than HCl. Also, due to highest electronegativity of fluorine, HF molecules involve intermolecular hydrogen bonding between them, thus, increasing the stability. So, option b is correct.
The enthalpies of formation of HF and HCI are -161 KJ and -92 KJ respe...
Explanation:
To determine which statement is incorrect, let's analyze each option one by one.
a) HF is more stable than HCl:
The enthalpy of formation for HF is -161 kJ/mol, while for HCl it is -92 kJ/mol. The enthalpy of formation is the energy change when one mole of a compound is formed from its constituent elements in their standard states. A more negative enthalpy of formation indicates a more stable compound. Since the enthalpy of formation for HF is more negative than that of HCl, it means that HF is more stable than HCl. Therefore, option 'a' is correct.
b) HCl are more stable than HF:
As mentioned above, the enthalpy of formation for HCl is -92 kJ/mol, which is less negative than the enthalpy of formation for HF (-161 kJ/mol). This implies that HCl is less stable than HF. Therefore, option 'b' is incorrect.
c) HF and HCl are exothermic compounds:
The negative enthalpy of formation for both HF and HCl indicates that these compounds release energy when they are formed. This energy release is characteristic of exothermic reactions. Therefore, option 'c' is correct.
d) Affinity of fluorine to hydrogen is greater than that of chlorine to hydrogen:
Affinity refers to the attraction or tendency of one element to bond with another element. In this case, the option states that fluorine has a greater affinity for hydrogen compared to chlorine. Since the enthalpy of formation for HF is more negative than that of HCl, it suggests that the bond between fluorine and hydrogen is stronger than the bond between chlorine and hydrogen. Therefore, option 'd' is correct.
In conclusion, the incorrect statement among the given options is 'b) HCl are more stable than HF'. The correct statement is that HF is more stable than HCl.
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