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As N is non metal so its hydride should be acidic in nature but the most stable and basic hydride of group 15 is NH3. Why?
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As N is non metal so its hydride should be acidic in nature but the mo...
Both NH3 ​and BiH3 ​have lone pair of electrons on the central atom and hence should behave as Lewis bases. But NH3 ​is much more basic than BiH3. This can be explained on the basis of electron density on the central atom. Atomic size of N(70 pm) is much smaller than that of Bi(148 pm). Therefore the electron density on N−atom is much higher than that on Bi−atom. Consequently, the tendency of N in NH3 ​to denote its pair of electrons is much higher than that of Bi in BiH3. Thus, NH3 ​is much more basic than BiH3 .
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As N is non metal so its hydride should be acidic in nature but the most stable and basic hydride of group 15 is NH3. Why?
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