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The relation between entropy change and heat energy?
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The relation between entropy change and heat energy?
The second law states that there exists a useful state variable called entropy. The change in entropy (delta S) is equal to the heat transfer (delta Q) divided by the temperature (T). For a given physical process, the entropy of the system and the environment will remain a constant if the process can be reversed. If we denote the initial and final states of the system by "i" and "f", Sf = Si (reversible). An example of a reversible process would be ideally forcing a flow through a constricted pipe. (Ideal means no boundary layer losses). As the flow moves through the constriction, the pressure, temperature and velocity would change, but these variables would return to their original values downstream of the constriction. The state of the gas would return to its original conditions and the change of entropy of the system would be zero. The second law states that if the physical process is irreversible, the entropy of the system and the environment must increase; the final entropy must be greater than the initial entropy. An example of an irreversible process is the problem discussed in the second paragraph where a hot object is put in contact with a cold object. Eventually, they both achieve the same equilibrium temperature. If we then separate the objects they do not naturally return to their original (different) temperatures. The process of bringing them to the same temperature is irreversible.
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The relation between entropy change and heat energy?
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