How many grams of silver could be plated out on a serving tray by pass...
How many grams of silver could be plated out on a serving tray by pass...
Solution:
Given data:
Time, t = 8 hours = 8 x 3600 s
Current, I = 9 A
Atomic mass of Ag = 107.8 g/mol
Density of Ag = 10 g/cm³
Thickness of silver plating, d = 0.002 cm
Step 1: Calculation of the amount of charge passed
The amount of charge passed, Q = I x t
Q = 9 A x 8 x 3600 s
Q = 2.592 x 10⁵ C
Step 2: Calculation of the amount of Ag deposited
From Faraday's law of electrolysis, the amount of Ag deposited is given by:
m = (Q x M) / (n x F)
where,
m = mass of Ag deposited (in grams)
Q = amount of charge passed (in coulombs)
M = atomic mass of Ag (in grams/mole)
n = number of electrons required for the reduction of one Ag+ ion (1 electron in this case)
F = Faraday constant (96,485 C/mol)
Substituting the values, we get:
m = (2.592 x 10⁵ C x 107.8 g/mol) / (1 x 96,485 C/mol)
m = 287.9 g
Therefore, 287.9 g of Ag can be plated out on the serving tray.
Step 3: Calculation of the area of the tray
The volume of the Ag deposited is given by:
V = m / ρ
where,
V = volume of Ag deposited (in cm³)
m = mass of Ag deposited (in grams)
ρ = density of Ag (in g/cm³)
Substituting the values, we get:
V = 287.9 g / 10 g/cm³
V = 28.79 cm³
The area of the tray can be calculated using the formula:
V = A x d
where,
A = area of the tray (in cm²)
d = thickness of the silver plating (in cm)
Substituting the values, we get:
28.79 cm³ = A x 0.002 cm
A = 14,395 cm²
Therefore, the area of the tray is 14,395 cm².
Conclusion:
Thus, 287.9 g of Ag can be plated out on the serving tray by passing electrolysis of a solution of Ag(1) salt for 8 hours at a current of 9 ampere. The area of the tray is 14,395 cm² if the thickness of the silver plating is 0.002 cm.
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