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How many grams of silver could be plated out on a serving tray by passing electrolysis of a solution of Ag (1) salt for 8 hours at a current of 9 ampere? What is the area of the tray, if thickness of the silver platting is 0.002cm? Density of silver is 10g/cm^3.( Atomic mass of Ag=107.8)?
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Solution:

Given data:

Time, t = 8 hours = 8 x 3600 s

Current, I = 9 A

Atomic mass of Ag = 107.8 g/mol

Density of Ag = 10 g/cm³

Thickness of silver plating, d = 0.002 cm



Step 1: Calculation of the amount of charge passed

The amount of charge passed, Q = I x t

Q = 9 A x 8 x 3600 s

Q = 2.592 x 10⁵ C



Step 2: Calculation of the amount of Ag deposited

From Faraday's law of electrolysis, the amount of Ag deposited is given by:

m = (Q x M) / (n x F)

where,

m = mass of Ag deposited (in grams)

Q = amount of charge passed (in coulombs)

M = atomic mass of Ag (in grams/mole)

n = number of electrons required for the reduction of one Ag+ ion (1 electron in this case)

F = Faraday constant (96,485 C/mol)



Substituting the values, we get:

m = (2.592 x 10⁵ C x 107.8 g/mol) / (1 x 96,485 C/mol)

m = 287.9 g

Therefore, 287.9 g of Ag can be plated out on the serving tray.



Step 3: Calculation of the area of the tray

The volume of the Ag deposited is given by:

V = m / ρ

where,

V = volume of Ag deposited (in cm³)

m = mass of Ag deposited (in grams)

ρ = density of Ag (in g/cm³)



Substituting the values, we get:

V = 287.9 g / 10 g/cm³

V = 28.79 cm³



The area of the tray can be calculated using the formula:

V = A x d

where,

A = area of the tray (in cm²)

d = thickness of the silver plating (in cm)



Substituting the values, we get:

28.79 cm³ = A x 0.002 cm

A = 14,395 cm²

Therefore, the area of the tray is 14,395 cm².



Conclusion:

Thus, 287.9 g of Ag can be plated out on the serving tray by passing electrolysis of a solution of Ag(1) salt for 8 hours at a current of 9 ampere. The area of the tray is 14,395 cm² if the thickness of the silver plating is 0.002 cm.
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How many grams of silver could be plated out on a serving tray by passing electrolysis of a solution of Ag (1) salt for 8 hours at a current of 9 ampere? What is the area of the tray, if thickness of the silver platting is 0.002cm? Density of silver is 10g/cm^3.( Atomic mass of Ag=107.8)?
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