Oxygen molecule is formed bya)One axial s-s overlap and one p-p axial ...
Configuration of O atom
Configuration of O molecule
σ bond of O = O is formed-by axial overlapping of p —p orbital while π bond is formed by sidewise overlapping of p —p orbital.
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Oxygen molecule is formed bya)One axial s-s overlap and one p-p axial ...
Formation of Oxygen Molecule
To understand the formation of an oxygen molecule, we need to look at the electron configuration and the bonding present in the molecule.
Electron Configuration of Oxygen
The atomic number of oxygen is 8, and its electronic configuration is 1s² 2s² 2p⁴. This means that oxygen has 6 valence electrons.
Bonding in Oxygen Molecule
Oxygen molecule (O₂) is formed by the combination of two oxygen atoms. Each oxygen atom contributes 6 valence electrons, resulting in a total of 12 valence electrons in the molecule.
Axial and Sidewise Overlaps
In the formation of a molecule, the valence electrons of the atoms can overlap in different ways. The axial overlap occurs along the axis between the two nuclei, while the sidewise overlap occurs perpendicular to the axis between the two nuclei.
Explanation of Answer Option 'D'
According to the given answer option 'D', the formation of an oxygen molecule involves one p-p axial overlap and one p-p sidewise overlap.
One p-p Axial Overlap
In the axial overlap, the p orbitals of the oxygen atoms align along the axis between the two nuclei. This overlap allows the sharing of electrons between the two oxygen atoms, resulting in the formation of a sigma (σ) bond. This bond is formed by the head-on overlap of two half-filled p orbitals.
One p-p Sidewise Overlap
In the sidewise overlap, the two remaining p orbitals of the oxygen atoms align parallel to each other. This overlap allows the sharing of electrons between the p orbitals, resulting in the formation of a pi (π) bond. This bond is formed by the sideways overlap of two parallel p orbitals.
Overall Bonding in Oxygen Molecule
Thus, the oxygen molecule is formed by one sigma (σ) bond and one pi (π) bond. The sigma (σ) bond is formed by the axial overlap, while the pi (π) bond is formed by the sidewise overlap.
Conclusion
In summary, the correct answer option 'D' states that the formation of an oxygen molecule involves one p-p axial overlap and one p-p sidewise overlap. This combination of overlaps leads to the formation of a sigma (σ) bond and a pi (π) bond, resulting in the stable oxygen molecule.
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