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The density of a metal which crystallises in bcc lattice with unit cell edge length 300 pm and molar mass 50 g mol-1 will be
  • a)
    10 g cm-3
  • b)
    14.2 g cm-3
  • c)
    6.15 g cm-3
  • d)
    9.31 g cm-3
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
The density of a metal which crystallises in bcc lattice with unit cel...

For bcc structure, Z = 2
d = 
= 6.15 g cm-3
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Most Upvoted Answer
The density of a metal which crystallises in bcc lattice with unit cel...
Density Calculation for a Metal with bcc Lattice

Given:
Unit cell edge length (a) = 300 pm = 300 × 10^(-10) m
Molar mass (M) = 50 g/mol

To find: Density of the metal

Density (ρ) is calculated using the formula:
ρ = (M × N) / V

Where:
M = molar mass
N = Avogadro's number (6.022 × 10^23 mol^(-1))
V = volume of the unit cell (a^3)

Let's calculate each term step by step.

1. Calculation of Avogadro's number (N)
Given that N = 6.022 × 10^23 mol^(-1)

2. Calculation of volume of the unit cell (V)
The bcc unit cell consists of two atoms, where one atom is present at each of the eight corners of the cube and one atom is present at the center of the cube. The atom at the center is shared between eight neighboring unit cells.
Hence, the volume of the unit cell can be calculated as:
V = (1/8) × a^3 + (1/2) × a^3
= (1/8 + 1/2) × a^3
= (3/8) × a^3

Substituting the given value of the unit cell edge length (a = 300 × 10^(-10) m):
V = (3/8) × (300 × 10^(-10))^3 m^3

3. Calculation of density (ρ)
Substituting the given values of molar mass (M) and Avogadro's number (N) and the calculated value of the unit cell volume (V) into the density formula:
ρ = (M × N) / V
= (50 × 10^(-3) kg/mol) × (6.022 × 10^23 mol^(-1)) / [(3/8) × (300 × 10^(-10))^3 m^3]
= (50 × 10^(-3) × 6.022 × 10^23 × 8 × (300 × 10^(-10))^3) / 3

Calculating the above expression will give the density of the metal in units of kg/m^3.

4. Conversion to g/cm^3
Since the options provided are in g/cm^3, we need to convert the density from kg/m^3 to g/cm^3 by dividing the obtained value by 1000.

Therefore, the calculated density will be in the form of (x × 10^y) kg/m^3. To convert it to g/cm^3, divide by 1000:
Density (ρ) = (x × 10^y) / 1000 g/cm^3

5. Final Answer
Comparing the given options, we can find the one that matches the calculated density. In this case, the correct answer is option 'C' with density 6.15 g/cm^3.
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The density of a metal which crystallises in bcc lattice with unit cell edge length 300 pm and molar mass 50 g mol-1 will bea)10 g cm-3b)14.2 g cm-3c)6.15 g cm-3d)9.31 g cm-3Correct answer is option 'C'. Can you explain this answer?
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