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What is the term for the property of amino acids where the structure changes in solutions of different pH due to the ionizable nature of -NH2 and -COOH groups?
  • a)
    Isomerism
  • b)
    Tautomeric shift
  • c)
    Hydrolysis
  • d)
    Acid dissociation
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
What is the term for the property of amino acids where the structure c...
  • Amino acids exhibit acid dissociation because their structure changes in solutions of different pH, primarily due to the ionizable nature of -NH2 and -COOH groups.
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What is the term for the property of amino acids where the structure c...
Acid dissociation is the term for the property of amino acids where the structure changes in solutions of different pH due to the ionizable nature of -NH2 and -COOH groups.

Explanation:

pH and the ionization of amino acids:
Amino acids are organic compounds that contain both an amino group (-NH2) and a carboxyl group (-COOH). These functional groups can ionize in solutions of different pH. The ionizable nature of these groups gives amino acids their characteristic acidic and basic properties.

Acid dissociation:
The -NH2 group of an amino acid acts as a weak base, while the -COOH group acts as a weak acid. In solutions of low pH (acidic solutions), the -COOH group tends to donate a proton (H+) and becomes ionized, forming a carboxylate ion (-COO-). This process is known as acid dissociation or ionization.

On the other hand, in solutions of high pH (basic solutions), the -NH2 group tends to accept a proton (H+) and becomes ionized, forming an amino ion (-NH3+). This process is also a type of acid dissociation or ionization.

Changes in structure:
As the amino acid undergoes acid dissociation, its structure changes due to the formation of charged species. The formation of carboxylate ions or amino ions introduces additional charges to the amino acid molecule.

These charged species can interact with other molecules or ions in the solution, leading to changes in the overall properties and behavior of the amino acid. For example, the solubility, reactivity, and binding affinity of the amino acid can be influenced by its ionization state.

Importance in biological systems:
The property of acid dissociation in amino acids is essential in biological systems. Amino acids are the building blocks of proteins, and the ionization of their functional groups plays a crucial role in protein structure, function, and stability.

The ionization state of amino acids also affects their behavior as buffers in biological systems. Buffers help maintain a stable pH within cells and tissues, which is crucial for various biochemical processes.

Overall, the property of acid dissociation in amino acids is a fundamental aspect of their chemistry and has significant implications in biology and biochemistry.
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What is the term for the property of amino acids where the structure changes in solutions of different pH due to the ionizable nature of -NH2 and -COOH groups?a)Isomerismb)Tautomeric shiftc)Hydrolysisd)Acid dissociationCorrect answer is option 'D'. Can you explain this answer?
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