Please explain following question : Which of the following order is co...
I think it's C.. Because bond order of N2O3 has high BP BP repulsion so bond angle is higher than N2O5
Please explain following question : Which of the following order is co...
Comparison of Compounds
To determine the correct order among the given options, let's analyze each one.
a) NO > N2O (Bond length of N-O)
- Reasoning: In nitric oxide (NO), the N-O bond is a double bond, while in nitrous oxide (N2O), the N-O bond is single. Double bonds are generally shorter than single bonds, hence NO has a shorter bond length compared to N2O.
b) N2O3 > N2O5 (Acidic character)
- Reasoning: N2O5 is a stronger acid than N2O3 due to the presence of more oxygen atoms, which can stabilize the negative charge on the conjugate base after deprotonation. Thus, this order is incorrect.
c) N2O3 > N2O5 (O-N-O bond angle)
- Reasoning: In N2O5, the structure is more complex with additional oxygen atoms leading to a change in hybridization and bond angles. N2O3 typically has a more bent structure, resulting in larger O-N-O angles compared to N2O5. This order is incorrect.
d) NO2 = N2O5 (O-N-O bond angles)
- Reasoning: Both NO2 and N2O5 have resonance structures that influence their bond angles. The O-N-O bond angle in both compounds is similar due to the trigonal planar arrangement around the nitrogen atom. Therefore, this order is correct.
Conclusion
The correct order is: d) NO2 = N2O5 (O-N-O bond angles). Other comparisons do not hold true based on chemical bonding and structural analysis.
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