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Consider the following reaction between alkyl halides, RX and alcoholic AgNO3:
RX + Ag → R+ + Ag+ X
Which of the following statements is true about the above reaction?
  • a)
    For a given alkyl group, the reactivity decreases in the order RCl > RBr > RI.
  • b)
    For a given halogen atom, reactivity decreases in the order 3° > 2° > 1°.
  • c)
    Racemisation does not occur.
  • d)
    Rearrangement of alkyl group always occurs.
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
Consider the following reaction between alkyl halides, RX and alcoholi...
Reactivity of alkyl halides in the given reaction:
- The reactivity of alkyl halides in the given reaction decreases in the order RCl > RBr > RI.
- This is because the strength of the carbon-halogen bond decreases in the order Cl > Br > I, making it easier for silver ions to replace the halogen atom in the alkyl halide.

Reactivity of alkyl halides based on the degree of carbon:
- The reactivity also depends on the degree of carbon in the alkyl halide, with tertiary (3°) alkyl halides being more reactive than secondary (2°) and primary (1°) alkyl halides.
- This is because the carbocation intermediate formed during the reaction is more stable in the case of tertiary alkyl halides, leading to higher reactivity.

Racemisation and rearrangement:
- Racemisation can occur in some cases where the reaction proceeds through a carbocation intermediate.
- Rearrangement of alkyl groups may or may not occur depending on the specific reaction conditions and the stability of possible carbocation intermediates.
Therefore, option B is the correct statement about the given reaction, as reactivity decreases in the order 3° > 2° > 1° for a given halogen atom in alkyl halides.
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Community Answer
Consider the following reaction between alkyl halides, RX and alcoholi...
The given reaction is SN1 type.
For alkyl group, the reactivity decreases in the order 3° > 2° > 1°.
So, (2) is correct.
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Consider the following reaction between alkyl halides, RX and alcoholic AgNO3:RX + Ag→ R++ Ag+X–Which of the following statements is true about the above reaction?a)For a given alkyl group, the reactivity decreases in the order RCl > RBr > RI.b)For a given halogen atom, reactivity decreases in the order 3° > 2° > 1°.c)Racemisation does not occur.d)Rearrangement of alkyl group always occurs.Correct answer is option 'B'. Can you explain this answer?
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Consider the following reaction between alkyl halides, RX and alcoholic AgNO3:RX + Ag→ R++ Ag+X–Which of the following statements is true about the above reaction?a)For a given alkyl group, the reactivity decreases in the order RCl > RBr > RI.b)For a given halogen atom, reactivity decreases in the order 3° > 2° > 1°.c)Racemisation does not occur.d)Rearrangement of alkyl group always occurs.Correct answer is option 'B'. Can you explain this answer? for NEET 2024 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about Consider the following reaction between alkyl halides, RX and alcoholic AgNO3:RX + Ag→ R++ Ag+X–Which of the following statements is true about the above reaction?a)For a given alkyl group, the reactivity decreases in the order RCl > RBr > RI.b)For a given halogen atom, reactivity decreases in the order 3° > 2° > 1°.c)Racemisation does not occur.d)Rearrangement of alkyl group always occurs.Correct answer is option 'B'. Can you explain this answer? covers all topics & solutions for NEET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Consider the following reaction between alkyl halides, RX and alcoholic AgNO3:RX + Ag→ R++ Ag+X–Which of the following statements is true about the above reaction?a)For a given alkyl group, the reactivity decreases in the order RCl > RBr > RI.b)For a given halogen atom, reactivity decreases in the order 3° > 2° > 1°.c)Racemisation does not occur.d)Rearrangement of alkyl group always occurs.Correct answer is option 'B'. Can you explain this answer?.
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