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Grignard reagents and organolithium compounds on addition to dry ice separately, followed by hydrolysis gives
  • a)
    ketones and carboxylic acids respectively
  • b)
    carboxylic acids and ketones respectively
  • c)
    only carboxylic acids
  • d)
    onty ketones
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Grignard reagents and organolithium compounds on addition to dry ice s...
ONLY CARBOXYL ACIDS
GRIGNARD REAGENT  react with dry ice (solid CO2)  followed by aqueous acid work-up to give carboxylic acids.
CO2 can be thought of as a being a dicarbonyl compound :  O=C=O
Note that the carboxylic acid contains one extra C atom compared to the original halide from which the Grignard reagent was prepared.
RMgX and RLi show same type of reeaction with dry ice.
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Grignard reagents and organolithium compounds on addition to dry ice separately, followed by hydrolysis givesa)ketones and carboxylic acids respectivelyb)carboxylic acids and ketones respectivelyc)only carboxylic acidsd)onty ketonesCorrect answer is option 'B'. Can you explain this answer?
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