What is the melting point order of B;Al;Ga;In and Tl .explain?
The melting point decreases down the group. the top element has large melting point because of the small size. further in some special cases like this one, thallium has more melting point than indium. so the order is ba>al>ga>tl>in
What is the melting point order of B;Al;Ga;In and Tl .explain?
Melting Point Order: B, Al, Ga, In, Tl
Explanation:
To understand the melting point order of the elements Boron (B), Aluminum (Al), Gallium (Ga), Indium (In), and Thallium (Tl), we need to consider their atomic structure and various factors that influence melting point.
Atomic Structure:
- Boron (B) has an atomic number of 5 and its electronic configuration is 1s² 2s² 2p¹.
- Aluminum (Al) has an atomic number of 13 and its electronic configuration is 1s² 2s² 2p⁶ 3s² 3p¹.
- Gallium (Ga) has an atomic number of 31 and its electronic configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p¹.
- Indium (In) has an atomic number of 49 and its electronic configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ 5s² 4d¹⁰ 5p¹.
- Thallium (Tl) has an atomic number of 81 and its electronic configuration is 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ 5s² 4d¹⁰ 5p⁶ 6s² 4f¹⁴ 5d¹⁰ 6p¹.
Influence of Atomic Structure:
- The melting point is influenced by the strength of the metallic bonds holding the atoms together.
- In metallic bonding, the valence electrons are delocalized, forming a "sea" of electrons that hold the positive metal ions together.
- The strength of metallic bonding increases with the number of valence electrons and the effective nuclear charge experienced by these electrons.
- As we move from left to right across a period in the periodic table, the effective nuclear charge increases, resulting in stronger metallic bonding and higher melting points.
Explanation of Melting Point Order:
- Boron (B) has the lowest melting point among the given elements due to its small atomic size and fewer valence electrons. The metallic bonding in boron is weaker compared to the other elements.
- Aluminum (Al) has a higher melting point than boron due to its larger atomic size and stronger metallic bonding resulting from increased valence electrons and effective nuclear charge.
- Gallium (Ga) has a higher melting point than aluminum because it has more valence electrons and a stronger effective nuclear charge.
- Indium (In) has a higher melting point than gallium due to its larger atomic size, increased valence electrons, and stronger metallic bonding.
- Thallium (Tl) has the highest melting point among the given elements as it possesses the largest atomic size, the highest number of valence electrons, and experiences the strongest effective nuclear charge.
Summary:
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