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Calculate the entropy change during the melting of one mole of ice into water at 0 degree Celsius and 1 atm pressure. Enthalpy of fusion of ice is 6008 J mol‐¹?
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Calculate the entropy change during the melting of one mole of ice int...
Entropy Change Calculation
To calculate the entropy change during the melting of ice at 0 °C and 1 atm, we can use the formula:
ΔS = ΔH/T
Where:
- ΔS = Change in entropy (J/K·mol)
- ΔH = Enthalpy of fusion (J/mol)
- T = Temperature (K)
Given Values
- Enthalpy of fusion (ΔH) = 6008 J/mol
- Temperature (T) = 0 °C = 273.15 K (converted to Kelvin)
Calculating Entropy Change
1. Convert Temperature to Kelvin:
- T = 0 °C + 273.15 = 273.15 K
2. Apply the Entropy Change Formula:
- ΔS = ΔH/T
- ΔS = 6008 J/mol / 273.15 K
3. Perform the Calculation:
- ΔS ≈ 22.0 J/K·mol
Significance of the Result
- The positive value of ΔS indicates an increase in disorder as ice melts into water.
- This is consistent with thermodynamic principles, where melting involves a transition from a structured solid to a less ordered liquid state.
Conclusion
- The entropy change during the melting of one mole of ice at 0 °C and 1 atm is approximately 22.0 J/K·mol.
- This change highlights the thermodynamic favorability of the melting process, reinforcing the concept of increased randomness in the system.
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Calculate the entropy change during the melting of one mole of ice into water at 0 degree Celsius and 1 atm pressure. Enthalpy of fusion of ice is 6008 J mol‐¹?
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