Calculate the no. of electrons required to deposit 40.5gm.of Al ?
Calculation of electrons required to deposit 40.5gm of Al
Introduction
Aluminum (Al) is a metal that is widely used in various industries due to its unique properties such as low density, high strength, and good conductivity. Electroplating is a process that is commonly used to coat a metal object with a thin layer of another metal, such as aluminum. In this process, a current is passed through a solution containing the metal ions to be deposited, and the metal ions are reduced to form a thin layer on the object. In this article, we will calculate the number of electrons required to deposit 40.5gm of aluminum using the Faraday's law of electrolysis.
Faraday's law of electrolysis
Faraday's law of electrolysis states that the amount of a substance deposited or liberated at an electrode during electrolysis is directly proportional to the quantity of electricity passed through the electrolyte.
The formula to calculate the amount of substance deposited is:
Amount of substance deposited = (Current x Time x Atomic weight) / (Number of electrons x Faraday's constant)
Where,
Current = the amount of electric current passing through the electrolyte (in amperes)
Time = the duration of electrolysis (in seconds)
Atomic weight = the atomic weight of the metal being deposited
Number of electrons = the number of electrons required to reduce one ion of the metal being deposited
Faraday's constant = 96,485 coulombs per mole of electrons
Calculation
In the case of aluminum, the atomic weight is 26.98 and the number of electrons required to reduce one ion of aluminum is 3. Therefore, the formula can be simplified as:
Amount of aluminum deposited = (Current x Time x 26.98) / (3 x 96,485)
To calculate the number of electrons required to deposit 40.5gm of aluminum, we need to rearrange the formula to solve for the current:
Current = (Amount of aluminum deposited x 3 x 96,485) / (Time x 26.98)
Assuming a current of 1 ampere and a time of 1 second, we can calculate the amount of aluminum deposited in grams:
Amount of aluminum deposited = (1 x 1 x 26.98) / (3 x 96,485) = 9.01 x 10^-5 g
Therefore, the number of electrons required to deposit 40.5gm of aluminum can be calculated as:
Number of electrons = (40.5 / 9.01 x 10^-5) x (3 x 96,485) = 1.02 x 10^23
Conclusion
In conclusion, the number of electrons required to deposit 40.5gm of aluminum using the Faraday's law of electrolysis is 1.02 x 10^23. This calculation shows the importance of understanding the principles of electroplating and the use of Faraday's law of electrolysis in various industries.