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Acidified solutions of sodium thiosulphate are unstable because in thiosulphate
- a)The two suphur atoms are at unstable oxidation state of +2
- b)The two sulphur atoms are at different oxidation state of +6 and -2
- c)The S-S bonds are unstable
- d)Thio compoinds contain S in oxidation state of zero
Correct answer is option 'B'. Can you explain this answer?
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Acidified solutions of sodium thiosulphate are unstable because in thi...
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Acidified solutions of sodium thiosulphate are unstable because in thi...
Explanation:
Sodium thiosulphate is a salt of thiosulphuric acid, which is a polythionic acid. Polythionic acids are unstable in acidified solutions due to the presence of multiple sulphur atoms and different oxidation states of sulphur.
The instability of acidified solutions of sodium thiosulphate is due to the following reasons:
- Different Oxidation States: Thiosulphate contains two sulphur atoms in different oxidation states, i.e., 6 and -2. This creates a potential for redox reactions, and the presence of acid further enhances the instability of the oxidation states.
- Disproportionation: In acidic solutions, thiosulphate undergoes disproportionation, which means that it undergoes both oxidation and reduction reactions. This leads to the formation of sulphur dioxide, sulphur, and sulphate ions. This reaction is also responsible for the bleaching property of sodium thiosulphate.
- Acid Hydrolysis: Acid hydrolysis of thiosulphate leads to the formation of sulphuric acid and sulphur dioxide. This reaction further enhances the instability of thiosulphate in acidic solutions.
Hence, the correct answer is option B, i.e., the two sulphur atoms are at different oxidation states of 6 and -2.
Sodium thiosulphate is a salt of thiosulphuric acid, which is a polythionic acid. Polythionic acids are unstable in acidified solutions due to the presence of multiple sulphur atoms and different oxidation states of sulphur.
The instability of acidified solutions of sodium thiosulphate is due to the following reasons:
- Different Oxidation States: Thiosulphate contains two sulphur atoms in different oxidation states, i.e., 6 and -2. This creates a potential for redox reactions, and the presence of acid further enhances the instability of the oxidation states.
- Disproportionation: In acidic solutions, thiosulphate undergoes disproportionation, which means that it undergoes both oxidation and reduction reactions. This leads to the formation of sulphur dioxide, sulphur, and sulphate ions. This reaction is also responsible for the bleaching property of sodium thiosulphate.
- Acid Hydrolysis: Acid hydrolysis of thiosulphate leads to the formation of sulphuric acid and sulphur dioxide. This reaction further enhances the instability of thiosulphate in acidic solutions.
Hence, the correct answer is option B, i.e., the two sulphur atoms are at different oxidation states of 6 and -2.
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Acidified solutions of sodium thiosulphate are unstable because in thi...
Option B is right
Na2So2O3+Hcl that gives 2 Nacl+So2+S+H2O sodium thiosulphate, in the presence of dilute acids decomposes to give So2 And S that's why option B is right
Na2So2O3+Hcl that gives 2 Nacl+So2+S+H2O sodium thiosulphate, in the presence of dilute acids decomposes to give So2 And S that's why option B is right
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Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer?
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Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer? for NEET 2024 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for NEET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer?.
Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer? for NEET 2024 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for NEET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer?.
Solutions for Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer? in English & in Hindi are available as part of our courses for NEET.
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Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer?, a detailed solution for Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer? has been provided alongside types of Acidified solutions of sodium thiosulphate are unstable because in thiosulphatea)The two suphur atoms are at unstable oxidation state of +2b)The two sulphur atoms are at different oxidation state of +6 and -2c)The S-S bonds are unstabled)Thio compoinds contain S in oxidation state of zeroCorrect answer is option 'B'. Can you explain this answer? theory, EduRev gives you an
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