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The shape of ClO₃⁻ according to valence shell electron repulsion theory will be
  • a)
    Planar triangle
  • b)
    Pyramidal
  • c)
    Tetrahedral
  • d)
    Square planar
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
The shape of ClO₃⁻ according to valence shell electron repulsion theor...
Explanation:
Valence Shell Electron Pair Repulsion (VSEPR) theory is used to predict the shapes of molecules based on the repulsion between their valence electrons. According to VSEPR theory, the ClO₃⁻ ion has a trigonal pyramid shape with a bond angle of approximately 107°.

Steps to determine the shape of ClO₃⁻ using VSEPR theory:

1. Determine the Lewis structure of ClO₃⁻:

- Chlorine (Cl) has 7 valence electrons and oxygen (O) has 6 valence electrons.
- There are three oxygen atoms bonded to the central Cl atom in ClO₃⁻.
- The total number of valence electrons is 7 + (3 x 6) + 1 = 22.
- The Lewis structure of ClO₃⁻ is:

O
/ \
O O
| |
Cl O⁻

2. Determine the electron group geometry:

- The ClO₃⁻ ion has four electron groups around the central Cl atom (three single bonds and one lone pair of electrons).
- The electron group geometry is therefore tetrahedral.

3. Determine the molecular geometry:

- To determine the molecular geometry, we need to take into account the lone pair of electrons on one of the oxygen atoms.
- The lone pair of electrons repels the bonding pairs, causing the ClO₃⁻ ion to adopt a trigonal pyramid shape.
- The bond angle between the Cl-O bonds is approximately 107°.

Conclusion:
According to VSEPR theory, the ClO₃⁻ ion has a trigonal pyramid shape with a bond angle of approximately 107°.
Free Test
Community Answer
The shape of ClO₃⁻ according to valence shell electron repulsion theor...
It has one lone pair electron
( valence electron of chlorine+charge/2)
7+1/2=4

lone pair= 4-3(here 3 oxygen atom )
= 1
ClO3^- has 1 lone pair and 3 shared pair electron. so, pyramidal geometry.
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The shape of ClO₃⁻ according to valence shell electron repulsion theory will bea)Planar triangleb)Pyramidalc)Tetrahedrald)Square planarCorrect answer is option 'B'. Can you explain this answer?
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