Which is chlorate (I) ion?
a)

b)

c)

d)

Correct answer i
s option 'B'. Can you explain this answer?

Pooja Shah answered
  • ClO3: A very reactive inorganic anion.
  • The term chlorate can also be used to describe any compound containing the chlorate ion, normally chlorate salts. 
  • Example: Potassium chlorate, KClO3

Which of the following is not an example of redox reaction?
  • a)
    BaCl2 + H2SO4 ⎯→ BaSO4 + 2HCl
  • b)
    Fe2O3 + 3CO ⎯→ 2Fe + 3CO2
  • c)
    2K + F2 ⎯→ 2KF
  • d)
    CuO + H2 ⎯→ Cu + H2O
Correct answer is option 'A'. Can you explain this answer?

Raghav Bansal answered
a) BaCl2 + H2SO4 → BaSO4 + 2HCl is not a redox reaction, as there is no change in the oxidation state of any element.
It is an example of double displacement reactions.

The oxidation half reaction for following reaction is
Fe2+(aq) + Cr2O72-(aq) → Fe3+ (aq) + Cr3+(aq)
  • a)
    Fe3+(aq) → Fe2+ (aq)
  • b)
    Cr2O72-(aq) → Cr3+(aq)
  • c)
    Cr3+(aq) → Cr2O72-(aq)
  • d)
    Fe2+ (aq) → Fe3+(aq)
Correct answer is option 'D'. Can you explain this answer?

Geetika Shah answered
Oxidation half reaction for a reaction is that reaction which gives us the reactant and product formed after the oxidation of the reactant. In this case Fe+2 oxidizes itself to Fe+3 and so the oxidation of Fe+2 is oxidation half reaction. Option d correct.

Oxidation numbers of P in PO4−3, of S in SO42− and that of Cr in Cr2O72− are respectively,
  • a)
     +5, +6 and +6
  • b)
    +3, +6 and +5
  • c)
    +5, +3 and +6               
  • d)
    -3, +6 and +6
Correct answer is option 'A'. Can you explain this answer?

Raghav Bansal answered
The correct answer is option A
(I) xPO43−​ ⇒ x + 4 × (−2) = −3
                ⇒x = −3 + 8 = +5
                ⇒x = +5
Oxidation number of P = +5
(II) xSO42−​ ⇒ x + 4 × (−2) = −2
                ⇒x = −2 + 8
                  ⇒x = +6
Oxidation number of S=+6
(III) xCr2​O72− ​    ⇒2x + 7 × (−2) = −2
                        ⇒2x =−2+14
                        ⇒2x=12
                        ⇒x= 12/2​ = +6

Oxidation number of 1/2 is assigned to oxygen atom in
  • a)
    superoxides
  • b)
    when oxygen is bonded to fluorine
  • c)
    when oxygen is bonded to metals
  • d)
    peroxidesperoxides
Correct answer is option 'A'. Can you explain this answer?

Arka Desai answered
The oxidation number is a concept used in chemistry to keep track of the distribution of electrons in a compound or molecule. It is a measure of the charge that an atom would have if all the shared electrons were assigned to the more electronegative atom in a bond.

In the case of oxygen, its most common oxidation number is -2. However, in certain compounds, such as superoxides and peroxides, the oxidation number of oxygen deviates from -2.

Oxidation number of 1/2 is assigned to the oxygen atom in superoxides. Superoxides are a class of compounds that contain the superoxide ion, O2-. In this ion, each oxygen atom has an oxidation number of -1/2. This is because the oxygen-oxygen bond in the superoxide ion is a single bond with a bond order of 1/2. Therefore, each oxygen atom is assigned an oxidation number of -1/2 to account for the distribution of electrons in the bond.

In the case of peroxides, such as hydrogen peroxide (H2O2), the oxidation number of oxygen is -1. In peroxides, the oxygen-oxygen bond is a single bond with a bond order of 1. Each oxygen atom is assigned an oxidation number of -1 to account for the distribution of electrons in the bond.

When oxygen is bonded to fluorine, the oxidation number of oxygen is -1. Fluorine is the most electronegative element, and therefore, it attracts the shared electrons in the bond more strongly than oxygen. As a result, oxygen is assigned an oxidation number of -1 to account for the unequal distribution of electrons in the bond.

When oxygen is bonded to metals, the oxidation number of oxygen is typically -2. However, there are some exceptions to this rule, such as in certain metal peroxides or superoxides, where the oxidation number of oxygen deviates from -2.

In summary, the oxidation number of 1/2 is assigned to the oxygen atom in superoxides, where the oxygen-oxygen bond is a single bond with a bond order of 1/2. In other compounds, such as peroxides, fluorides, and most metal oxides, the oxidation number of oxygen is typically -1 or -2.

In Daniel cell, oxidation takes place at
  • a)
    Any of the two electrodes
  • b)
    Depends on the salts and their solutions
  • c)
    Anode
  • d)
    Cathode
Correct answer is option 'C'. Can you explain this answer?

Rohit Shah answered
The solutions in which the electrodes are immersed are called electrolytes. The chemical reaction that takes place in a galvanic cell is the redox reaction. One electrode acts as anode in which oxidation takes place and the other acts as the cathode in which reduction takes place.

Hydrogen is prepared from H2O by adding
  • a)
    Ag, which acts as reducing agent
  • b)
    Ca, which acts as reducing agent
  • c)
    Au, which acts as oxidising agent
  • d)
    AI, which acts as oxidising agent
Correct answer is option 'B'. Can you explain this answer?

Saumya Dey answered
Preparation of Hydrogen from Water

- Hydrogen gas can be prepared from water by using a reducing agent, which reduces water to hydrogen gas and also gets oxidized in the process.
- Calcium (Ca) is a good reducing agent and can be used to prepare hydrogen gas from water.
- When calcium is added to water, it reacts with water to form calcium hydroxide and hydrogen gas.
- The chemical equation for the reaction is:

Ca + 2H2O → Ca(OH)2 + H2

- Calcium has a strong affinity for oxygen and readily reacts with water to form calcium hydroxide, liberating hydrogen gas.
- This reaction is exothermic and produces a considerable amount of heat, which can be used to heat water or other substances.
- The liberated hydrogen gas can be collected by upward displacement of air or by using a gas syringe or gas jar.
- The purity of hydrogen gas prepared by this method is relatively low, as it may contain impurities like calcium hydroxide, unreacted water, and other gases like nitrogen and oxygen.
- Therefore, additional purification steps may be required to obtain pure hydrogen gas.

Advantages of using Calcium as a reducing agent

- Calcium is a readily available and inexpensive reducing agent.
- It reacts readily with water, producing a large amount of hydrogen gas.
- The reaction is exothermic and produces heat, which can be utilized in other processes.
- Calcium is a relatively safe reducing agent, as it does not react violently with water or other substances.
- The by-products of the reaction, calcium hydroxide, and hydrogen gas, are non-toxic and can be disposed of safely.

The reduction potential values of M, N and O are +2.46, -1.13 and -3.13 V respectively. Which of the following order is correct regarding their reducing property?
  • a)
    M>N>O
  • b)
    O>M>N
  • c)
    M>O>N
  • d)
    O>N>M
Correct answer is option 'D'. Can you explain this answer?

Geetika Shah answered
Reduction potential means the tendency to reduce itself, i.e SO if we need reducing agent, then we need elements having more oxidising potential or reversing reduction potential order.
The order of reduction potential - O < N < M
So the order of reducing agent = M < N < O

Select the set of compounds with oxidation-reduction duality.
  • a)
    Cl2, H3PO4, HCHO, HNO2
  • b)
    Cl2, H3PO3, C6H5CHO, H2O2
  • c)
    Br2, H3PO2, CH3CHO, H3PO4
  • d)
    CrO2Cl2, KMnO4, SO3, CO2
Correct answer is option 'B'. Can you explain this answer?

Neha Sharma answered
Com pounds having oxidising and reducing nature in given reaction are said to have oxidation-reduction duality. Such compounds are said to undergo disproportionation reaction.



(This is called Cannizzaro reaction.)

Note Such compounds have O.N. of the affected atoms intermediate of oxidation part and reduction part

In the following questions a statement of assertion (A) followed by a statement of reason (R) is given. Choose the correct option out of the choices given below each question. 
Assertion(A): Among halogens fluorine is the best oxidant.
Reason(R): Fluorine is the most electronegative atom.
  • a)
    Both A and R are true and R is the correct explanation of A.
  • b)
    Both A and R are true and R is not the correct explanation of A.
  • c)
    Both A and R are false.
  • d)
    A is true but R is false.
Correct answer is option 'B'. Can you explain this answer?

Dhruba Patel answered
Assertion(A): Among halogens fluorine is the best oxidant.
Reason(R): Fluorine is the most electronegative atom.

The correct answer is option B: Both A and R are true and R is not the correct explanation of A.

Explanation:
Assertion:
Fluorine is the best oxidant among halogens. An oxidant is a substance that accepts electrons from another substance during a chemical reaction. Fluorine has a high tendency to gain one electron to achieve a stable electron configuration, making it a strong oxidant.

Reason:
Fluorine is the most electronegative atom. Electronegativity is the measure of an atom's ability to attract electrons towards itself in a chemical bond. Fluorine has the highest electronegativity value among all the elements, indicating its strong ability to attract electrons. This high electronegativity makes fluorine highly reactive and a strong oxidant.

Explanation of the Correct Answer:
Both the assertion and reason are true. Fluorine is indeed the best oxidant among halogens due to its high tendency to gain electrons. Additionally, fluorine is the most electronegative atom, which explains its strong oxidizing power. However, the reason provided does not directly explain why fluorine is the best oxidant among halogens. Other factors such as atomic size and electron shielding also play a role in determining the oxidizing power of halogens. Therefore, the reason is not the correct explanation of the assertion.

In conclusion, fluorine's high electronegativity and strong tendency to gain electrons make it the best oxidant among halogens. However, its status as the best oxidant cannot be solely attributed to its electronegativity.

The oxidation number of oxygen in most compounds is
  • a)
    -3
  • b)
    1
  • c)
    4
  • d)
    -2.0
Correct answer is option 'D'. Can you explain this answer?

Niharika Nair answered
Oxidation number of oxygen in most compounds is -2.

Explanation:
- Oxidation number is the number assigned to an atom to indicate its degree of oxidation or loss/gain of electrons.
- Oxygen is a highly electronegative element, meaning it has a strong tendency to attract electrons.
- In most compounds, oxygen has an oxidation number of -2 because it tends to gain electrons to achieve a stable octet configuration (8 valence electrons).
- For example, in water (H2O), each hydrogen atom has an oxidation number of +1 and the oxygen atom has an oxidation number of -2, which balances out the charge to zero.
- There are some exceptions to this rule, such as in peroxides where oxygen has an oxidation number of -1, and in compounds with more electronegative elements where oxygen may have a positive oxidation number.
- Overall, the oxidation number of oxygen in most compounds is -2.

Equivalent weight of H3PO2 in a reaction is found to be half of its molecular weight. It can be due to its
  • a)
    reaction of two H+ ion
  • b)
    oxidation of H3PO3
  • c)
    oxidation of H3PO4
  • d)
    reduction of PH3
Correct answer is option 'B'. Can you explain this answer?

Anisha Chauhan answered
An equivalent weight of H3PO2 when it disproportionates into PH3 and H3PO3 is
For disproportionation reactions, use a trick to find equivalent mass; E = E1 + E2; where E1 and E2 are equivalent masses of oxidation and reduction half-reactions of the same element.
Now, find the n-factor(total change in oxidation number per molecule) and then equivalent mass = molar mass/n-factor.
So, when H3PO2 changes into PH3, the oxidation state of phosphorous changes from +1 to -3 so as n-factor is 4. Also when H3PO2 changes into H3PO3, the oxidation state of phosphorous changes from +1 to +5 so as n-factor is again 4.
Now equivalent mass of H3PO2, E =(M/4) + (M/4) = M/2
Hence, the correct option is b.

 In this method, the two half equations are balanced separately and then added together to give balanced equation
  • a)
    Reluctant method
  • b)
    Oxidizing agent method
  • c)
    Reducing agent method
  • d)
    Half reaction method
Correct answer is option 'D'. Can you explain this answer?

Kavita Joshi answered
In the ion-electron method (also called the half-reaction method), the redox equation is separated into two half-equations - one for oxidation and one for reduction. Each of these half-reactions is balanced separately and then combined to give the balanced redox equation.

Intensity of blue colour increases gradually when _________________
  • a)
    copper rod is dipped in silver nitrate solution
  • b)
    silver rod is dipped in copper nitrate solution
  • c)
    zinc rod is dipped in silver solution
  • d)
    copper rod is dipped in zinc rod solution
Correct answer is option 'A'. Can you explain this answer?

EduRev NEET answered
When a copper rod is dipped in silver nitrate solution, a redox reaction occurs between Copper and an aqueous solution of silver nitrate.
  • So the intensity of blue colour increases gradually as silver deposits on the rod.

The correct order of N-compounds in its decreasing order of oxidation states is
  • a)
    HNO3, NO, N2, NH4Cl
  • b)
    HNO3, NO, NH4Cl, N2
  • c)
    HNO3, NH4Cl, NO, N2
  • d)
    NH4Cl, N2, NO, HN03
Correct answer is option 'A'. Can you explain this answer?

To determine the decreasing order of oxidation states of nitrogen in the given compounds, we need to find the oxidation state of nitrogen in each compound:
  1. HNO3 (Nitric acid): Oxidation state of nitrogen: +5
  2. NO (Nitric oxide): Oxidation state of nitrogen: +2
  3. N2 (Dinitrogen): Oxidation state of nitrogen: 0
  4. NH4Cl (Ammonium chloride): Oxidation state of nitrogen: -3
Now, let's arrange these compounds in decreasing order of oxidation states:
  • HNO3: +5
  • NO: +2
  • N2: 0
  • NH4Cl: -3
So, the correct order in decreasing oxidation state is:
HNO3, NO, N2, NH4Cl

The process in which the strength of an unknown solution is calculated using a known standard solution.
  • a)
    Titration
  • b)
    Oxidation
  • c)
    Reduction
  • d)
    None of these
Correct answer is option 'A'. Can you explain this answer?

Nandini Iyer answered
A titration is a technique used to work out the concentration of an unknown solution based on its chemical reaction with a solution of known concentration. The process usually involves adding the known solution (the titrant) to a known quantity of the unknown solution (the analyte) until the reaction is complete.

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.
Assertion (A): In the reaction between potassium permanganate and potassium iodide, permanganate ions act as oxidising agent.
Reason (R) : Oxidation state of manganese changes from +2 to +7 during
the reaction.
  • a)
    Both A and R are true and R is the correct explanation of A.
  • b)
    Both A and R are true but R is not the correct explanation of A.
  • c)
    A is true but R is false.
  • d)
    Both A and R are false.
Correct answer is option 'C'. Can you explain this answer?

Manasa Patel answered
Assertion (A) Explained
In the reaction between potassium permanganate (KMnO4) and potassium iodide (KI):
- Potassium Permanganate as an Oxidizing Agent:
- Potassium permanganate contains manganese in the +7 oxidation state.
- In acidic conditions, KMnO4 can reduce to Mn^2+ (where manganese has an oxidation state of +2), which indicates that it acts as an oxidizing agent.
- Therefore, Assertion (A) is true.
Reason (R) Explained
- Oxidation State Change:
- The reason states that the oxidation state of manganese changes from +2 to +7.
- This is incorrect; in the reaction, manganese is reduced from +7 to +2, not the other way around.
- Therefore, Reason (R) is false.
Conclusion
- Since Assertion (A) is true and Reason (R) is false, the correct answer is:
- Option (C): A is true but R is false.
This analysis clarifies that while potassium permanganate behaves as an oxidizing agent in the reaction, the stated change in the oxidation state of manganese is inaccurately described in Reason (R).

Which of the following is true as per metal activity series?
  • a)
    Zn>Cu>Ag
  • b)
    Zn<Cu<Ag
  • c)
    Zn>Ag>Cu
  • d)
    Zn<Ag<Cu
Correct answer is option 'A'. Can you explain this answer?

EduRev NEET answered
Metal activity series or electrochemical series is a series in the decreasing order of metals which are active during a chemical reaction comparatively with each other.
  • Here, Zinc’s activity is greater than Copper’s activity and Copper’s activity is greater than that of silver.

When a zinc rod is kept in a copper nitrate solution what happens?
  • a)
    zinc is deposited on copper
  • b)
    copper is deposited in the beaker
  • c)
    zinc is deposited in the beaker
  • d)
    copper is deposited on zinc
Correct answer is option 'D'. Can you explain this answer?

EduRev NEET answered
When zinc is placed in copper nitrate solution the intensity of the blue colour is produced and copper iron is deposited on zinc.
  • This is a Redox reaction between zinc and an aqueous solution of copper nitrate occurring in a beaker.

 A standard hydrogen electrode has zero electrode potential because
  • a)
    Hydrogen is the lightest element
  • b)
    Hydrogen atom has only one electron.
  • c)
    Hydrogen is easiest to oxidize
  • d)
    The electrode potential is assumed to be zero
Correct answer is option 'D'. Can you explain this answer?

Rashi Sharma answered
Explanation:

A standard hydrogen electrode (SHE) is an electrode that is used as a reference in half-cell reactions to determine the electrode potential of other electrodes. It consists of a platinum electrode immersed in a solution of an acid, typically 1 M HCl, with hydrogen gas bubbling through it.

The electrode potential of a standard hydrogen electrode is considered to be zero because it is used as a reference point to measure the electrode potential of other electrodes. By convention, the electrode potential of the SHE is set to zero, and all other electrode potentials are measured relative to it.

The reasons why the electrode potential of the standard hydrogen electrode is assumed to be zero are as follows:

1. Consistency and ease of measurement: By establishing the electrode potential of the SHE as zero, it provides a consistent reference point for comparing the electrode potentials of other electrodes. This makes it easier to measure and compare the electrode potentials of different reactions.

2. Hydrogen as a neutral element: Hydrogen gas (H2) is composed of two hydrogen atoms, each with one electron. These electrons can easily be lost or gained, making hydrogen a versatile element for redox reactions. Since hydrogen is a neutral element, it is considered to have an electrode potential of zero.

3. Reversibility of the hydrogen electrode: The hydrogen electrode is reversible, meaning that it can be easily converted between an oxidation half-reaction and a reduction half-reaction. This reversibility allows for accurate and reproducible measurements of electrode potentials.

4. Standardization: The choice of the standard hydrogen electrode as the reference electrode is based on convention and standardization. It provides a consistent and universally accepted reference point for measuring and comparing electrode potentials.

Overall, the assumption of a zero electrode potential for the standard hydrogen electrode simplifies the measurement and comparison of electrode potentials in electrochemical reactions. It provides a consistent reference point and allows for the standardization of electrode potential measurements.

In the following reaction,
 
One equivalent of H2S (g)will reduce
  • a)
    1 Mole SO2
  • b)
    0.5 Mole SO2
  • c)
    0.25 Mole SO2
  • d)
    2 Mole SO2
Correct answer is option 'C'. Can you explain this answer?

Rithika Khanna answered

Change in oxidation number of S of H2S = 2 units
Change in oxidation number of S of SO2 = 4 units
Then one mole H2S = 2 equivalents H2S
One mole SO2 = 4 equivalent SO2
One equivalent H23 one equivalent SO2 = 0.25 mole SO2 

A metal in a compound can be displaced by another metal in the uncombined state. Which metal is a better reducing agent in such a case?
  • a)
    Better reducing agent is the one that looses more electrons
  • b)
    Better reducing agent is the one that looses less electrons
  • c)
    Both are same in reducing capacity
  • d)
    The reduced metal is a better reducing agent than the reducing metal
Correct answer is option 'A'. Can you explain this answer?

Bhavana Chavan answered
Concept of Reducing Agent:
A reducing agent is a substance that loses or "donates" an electron to another substance in a redox chemical reaction. Therefore, a good reducing agent is the one that gets oxidized easily, or in other words, the one that can easily lose electrons.

Characteristics of a Good Reducing Agent:
  • Electron Loss: A better reducing agent is the one that loses more electrons. This is because by losing electrons, the reducing agent gets oxidized and in turn reduces the other substance. This is the basic principle of a redox reaction.
  • Reactivity: The reactivity of the metal also determines its capacity as a reducing agent. Metals that are high in the reactivity series are good reducing agents. This is because they can easily lose electrons and get oxidized.
  • Stability: Metals that are less stable are better reducing agents because they can easily lose electrons to attain a stable state.
Hence, Option A is the correct answer - a better reducing agent is the one that loses more electrons.

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