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Does this compound shows optical isomerism Cl-CH=C=C=CH-Cl?
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Does this compound shows optical isomerism Cl-CH=C=C=CH-Cl?
Probably not. It's a cumulene system with odd number of consecutive double bonds. So it shows only geometrical isomerism not optical.
Community Answer
Does this compound shows optical isomerism Cl-CH=C=C=CH-Cl?
Understanding Optical Isomerism
Optical isomerism occurs due to the presence of chiral centers in a molecule. A chiral center is typically a carbon atom bonded to four different substituents, leading to non-superimposable mirror images.
Analyzing Cl-CH=C=C=CH-Cl
1. Structure Overview
- The compound Cl-CH=C=C=CH-Cl features a linear arrangement with two chlorine atoms at both ends.
2. Chirality Assessment
- For optical isomerism to occur, we need to identify chiral centers.
- In this molecule, the carbon atoms involved in the double bonds do not have four distinct groups attached to them.
- Each carbon in the double bond is bonded to either a hydrogen or another carbon and has the same substituents on either side.
3. Symmetry Consideration
- The presence of two chlorine atoms at the terminal ends introduces symmetry.
- This symmetry implies that the molecule can be superimposed on its mirror image, negating the possibility of chirality.
Conclusion
- The compound Cl-CH=C=C=CH-Cl does not exhibit optical isomerism due to the lack of chiral centers and the symmetry present in its structure.
- Without chirality, it cannot form non-superimposable mirror images, which are essential for optical isomerism.
This assessment reinforces the idea that optical isomerism is highly dependent on the structural arrangement of substituents around chiral centers.
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Does this compound shows optical isomerism Cl-CH=C=C=CH-Cl?
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