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Which one of the following complexes is not expected to exhibit isomerism [Ni(NH3)4(H2O)2]^2 Or [Ni(NH3)2Cl2]?
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Which one of the following complexes is not expected to exhibit isomer...
` Explanation:`
`Isomerism in Coordination Compounds:`
Isomerism in coordination compounds arises due to different spatial arrangements of ligands around the central metal atom. The two main types of isomerism are structural isomerism and stereoisomerism.
`Structural Isomerism:`
Structural isomerism can be further divided into coordination isomerism, linkage isomerism, and ionization isomerism. This type of isomerism arises due to different connectivity of ligands to the central metal atom.
`Stereoisomerism:`
Stereoisomerism can be further divided into geometrical isomerism and optical isomerism. Geometrical isomerism arises due to different spatial arrangements of ligands around the central metal atom.
`Analysis of the Complexes:`
1. `[Ni(NH3)4(H2O)2]^2`
This complex has 4 ammine ligands and 2 water ligands. Since all ligands are monodentate and there are no chelating ligands present, this complex is expected to exhibit stereoisomerism due to the possibility of geometrical isomerism.
2. `[Ni(NH3)2Cl2]`
This complex has 2 ammine ligands and 2 chloride ligands. Since all ligands are monodentate, this complex is also expected to exhibit stereoisomerism due to the possibility of geometrical isomerism.
`Conclusion:`
Both complexes are expected to exhibit stereoisomerism, specifically geometrical isomerism. Therefore, neither of the complexes is not expected to exhibit isomerism.
Community Answer
Which one of the following complexes is not expected to exhibit isomer...
[Ni(NH3)2Cl2]
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Which one of the following complexes is not expected to exhibit isomerism [Ni(NH3)4(H2O)2]^2 Or [Ni(NH3)2Cl2]?
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