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In reaction of alcohols with alkali metal, carboxylic acid etc., which of the following alcohol will react fastest?
  • a)
    Secondary
  • b)
    Tertiary
  • c)
    Primary
  • d)
    All equal
Correct answer is option 'C'. Can you explain this answer?
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In reaction of alcohols with alkali metal, carboxylic acid etc., which...
As the cation of primary alcohol is less stable so it will react faster than other alcohol to attain stability..
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In reaction of alcohols with alkali metal, carboxylic acid etc., which...

Primary alcohols react fastest in reactions with alkali metals, carboxylic acids, etc.

Primary alcohols have a higher reactivity compared to secondary and tertiary alcohols due to the presence of a primary carbon that is directly attached to the hydroxyl group. This primary carbon is more exposed and accessible for reactions, leading to faster reaction rates.

Here are some reasons why primary alcohols react fastest:

- Stability of the intermediate carbocation: Primary alcohols form a more stable carbocation intermediate compared to secondary and tertiary alcohols, which facilitates faster reactions.
- Hydrogen bonding: Primary alcohols can form stronger hydrogen bonds with the reacting species, promoting faster reaction rates.
- Stearic hindrance: Secondary and tertiary alcohols have more steric hindrance due to the presence of alkyl groups, which can slow down the reaction rate by hindering the approach of the reacting species.

Therefore, in reactions with alkali metals, carboxylic acids, etc., primary alcohols are the fastest to react due to their higher reactivity and accessibility of the primary carbon for reaction.
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In reaction of alcohols with alkali metal, carboxylic acid etc., which of the following alcohol will react fastest?a) Secondary b) Tertiary c) Primary d) All equal Correct answer is option 'C'. Can you explain this answer?
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