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Write the reaction of Rosenmund reduction ?
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Write the reaction of Rosenmund reduction ?
Rosenmund Reduction

The Rosenmund reduction is a type of reaction that is used to convert an acid chloride to an aldehyde. It is named after the Swiss chemist Karl Wilhelm Rosenmund who first discovered this reaction in 1918.

Reaction Mechanism

The Rosenmund reduction is a catalytic hydrogenation reaction that involves the following steps:

1. The acid chloride is first treated with palladium on charcoal (Pd/C) in the presence of hydrogen gas (H2).

2. The Pd/C catalyst adsorbs hydrogen gas onto its surface.

3. The acid chloride is then adsorbed onto the surface of the Pd/C catalyst.

4. The hydrogen gas is then transferred from the Pd/C catalyst to the acid chloride, which results in the formation of an aldehyde.

5. The aldehyde is then desorbed from the surface of the Pd/C catalyst.

6. The Pd/C catalyst can then be reused for subsequent reactions.

Applications

The Rosenmund reduction is a useful reaction in organic chemistry for the following reasons:

1. It allows for the conversion of acid chlorides to aldehydes, which are important intermediate compounds in the synthesis of various organic compounds.

2. It is a relatively mild reaction that can be carried out under ambient conditions.

3. The Pd/C catalyst is readily available and can be reused multiple times, which makes the reaction cost-effective.

Conclusion

The Rosenmund reduction is a catalytic hydrogenation reaction that is used to convert acid chlorides to aldehydes. It involves the use of palladium on charcoal as a catalyst and hydrogen gas under ambient conditions. The reaction is important in organic chemistry for the synthesis of various organic compounds.
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Write the reaction of Rosenmund reduction ?
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