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Dimerisation in carboxylic acid is due to
- a)ionic bond
- b)covalent bond
- c)coordinate bond
- d)intermolecular hydrogen bond
Correct answer is option 'D'. Can you explain this answer?
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Dimerisation in carboxylic acid is due toa)ionic bondb)covalent bondc)...
Carboxylic acids form dimers by hydrogen bonding of the acidic hydrogen and the carbonyl oxygen when anhydrous.
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Dimerisation in carboxylic acid is due toa)ionic bondb)covalent bondc)...
Intermolecular Hydrogen Bonding in Carboxylic Acid Dimerization
Carboxylic acids are organic compounds containing a carboxyl group (-COOH). When carboxylic acids are in a concentrated form or in a non-polar solvent, they tend to form dimers through intermolecular hydrogen bonding.
Intermolecular Hydrogen Bonding
- Intermolecular hydrogen bonding occurs between the hydrogen of one carboxylic acid molecule and the oxygen of another carboxylic acid molecule.
- The hydrogen bond formed is a type of weak dipole-dipole interaction.
- This hydrogen bonding leads to the formation of a dimer, where two carboxylic acid molecules are held together through hydrogen bonds.
Role of Hydrogen Bonding in Dimerization
- The presence of hydrogen bonding between carboxylic acid molecules stabilizes the dimer structure.
- This dimerization process is reversible, meaning the dimers can break apart and reform depending on the conditions.
Importance of Dimerization
- Dimerization of carboxylic acids affects their physical properties such as melting point, boiling point, and solubility.
- It also influences the reactivity of carboxylic acids in various chemical reactions.
In conclusion, dimerization in carboxylic acids is due to intermolecular hydrogen bonding, which plays a significant role in the structure and properties of these organic compounds.
Carboxylic acids are organic compounds containing a carboxyl group (-COOH). When carboxylic acids are in a concentrated form or in a non-polar solvent, they tend to form dimers through intermolecular hydrogen bonding.
Intermolecular Hydrogen Bonding
- Intermolecular hydrogen bonding occurs between the hydrogen of one carboxylic acid molecule and the oxygen of another carboxylic acid molecule.
- The hydrogen bond formed is a type of weak dipole-dipole interaction.
- This hydrogen bonding leads to the formation of a dimer, where two carboxylic acid molecules are held together through hydrogen bonds.
Role of Hydrogen Bonding in Dimerization
- The presence of hydrogen bonding between carboxylic acid molecules stabilizes the dimer structure.
- This dimerization process is reversible, meaning the dimers can break apart and reform depending on the conditions.
Importance of Dimerization
- Dimerization of carboxylic acids affects their physical properties such as melting point, boiling point, and solubility.
- It also influences the reactivity of carboxylic acids in various chemical reactions.
In conclusion, dimerization in carboxylic acids is due to intermolecular hydrogen bonding, which plays a significant role in the structure and properties of these organic compounds.
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Dimerisation in carboxylic acid is due toa)ionic bondb)covalent bondc)coordinate bondd)intermolecular hydrogen bondCorrect answer is option 'D'. Can you explain this answer?
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