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Dimerisation in carboxylic acid is due to
  • a)
    ionic bond
  • b)
    covalent bond
  • c)
    coordinate bond
  • d)
    intermolecular hydrogen bond
Correct answer is option 'D'. Can you explain this answer?
Most Upvoted Answer
Dimerisation in carboxylic acid is due toa)ionic bondb)covalent bondc)...
Carboxylic acids form dimers by hydrogen bonding of the acidic hydrogen and the carbonyl oxygen when anhydrous.
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Dimerisation in carboxylic acid is due toa)ionic bondb)covalent bondc)...
Intermolecular Hydrogen Bonding in Carboxylic Acid Dimerization
Carboxylic acids are organic compounds containing a carboxyl group (-COOH). When carboxylic acids are in a concentrated form or in a non-polar solvent, they tend to form dimers through intermolecular hydrogen bonding.

Intermolecular Hydrogen Bonding
- Intermolecular hydrogen bonding occurs between the hydrogen of one carboxylic acid molecule and the oxygen of another carboxylic acid molecule.
- The hydrogen bond formed is a type of weak dipole-dipole interaction.
- This hydrogen bonding leads to the formation of a dimer, where two carboxylic acid molecules are held together through hydrogen bonds.

Role of Hydrogen Bonding in Dimerization
- The presence of hydrogen bonding between carboxylic acid molecules stabilizes the dimer structure.
- This dimerization process is reversible, meaning the dimers can break apart and reform depending on the conditions.

Importance of Dimerization
- Dimerization of carboxylic acids affects their physical properties such as melting point, boiling point, and solubility.
- It also influences the reactivity of carboxylic acids in various chemical reactions.
In conclusion, dimerization in carboxylic acids is due to intermolecular hydrogen bonding, which plays a significant role in the structure and properties of these organic compounds.
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Dimerisation in carboxylic acid is due toa)ionic bondb)covalent bondc)coordinate bondd)intermolecular hydrogen bondCorrect answer is option 'D'. Can you explain this answer?
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