Esterification of carboxylic acids is a/an __________ reaction.a)Irrev...
Esterification of carboxylic acids is a nucleophilic substitution reaction.
Nucleophilic substitution reactions involve the substitution of a nucleophile with a leaving group. In the case of esterification, the carboxylic acid acts as the nucleophile and reacts with an alcohol to form an ester.
Here is a detailed explanation of why esterification is a nucleophilic substitution reaction:
1. Reaction mechanism:
The reaction proceeds through a two-step mechanism:
a. Protonation: The carboxylic acid molecule donates a proton to the alcohol, forming an oxonium ion. This step is facilitated by the presence of an acid catalyst (usually sulfuric acid).
b. Nucleophilic attack: The nucleophilic oxygen of the carboxylic acid attacks the electrophilic carbon of the oxonium ion, resulting in the formation of an ester and a water molecule. The oxonium ion is the leaving group in this reaction.
2. Role of the nucleophile and leaving group:
In esterification, the carboxylic acid serves as the nucleophile as it donates a pair of electrons to the electrophilic carbon. The alcohol molecule, on the other hand, acts as the leaving group as it leaves the molecule. The nucleophile replaces the leaving group, leading to the formation of the ester.
3. Characteristics of nucleophilic substitution reactions:
Nucleophilic substitution reactions typically involve the attack of a nucleophile on an electrophilic center, resulting in the substitution of a leaving group. These reactions are reversible in nature, meaning that they can proceed in both forward and backward directions. However, in esterification, the reaction is usually driven towards the formation of the ester by using an excess of the alcohol or by removing the water formed.
In summary, esterification of carboxylic acids is a nucleophilic substitution reaction because it involves the attack of a nucleophile (carboxylic acid) on an electrophilic center (oxonium ion), resulting in the substitution of a leaving group (alcohol).
Esterification of carboxylic acids is a/an __________ reaction.a)Irrev...
When carboxylic acids are heated with alcohols with suitable catalyst, esters are formed. This is a reversible reaction due to all the individual steps involved in the mechanism of this reaction are reversible in nature. It is a type of nucleophilic acyl substitution reaction.
To make sure you are not studying endlessly, EduRev has designed NEET study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in NEET.