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The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will be
- a)6000cm−1
- b)16000cm−1
- c)18000cm−1
- d)8000cm−1
Correct answer is option 'D'. Can you explain this answer?
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The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000c...
To determine the crystal field stabilization energy (CFSE) for [CoCl4]2-, we can use the relationship between the CFSE values of different coordination complexes.
The CFSE of [CoCl6]4- is given as 18000 cm-1. This means that the energy difference between the d orbitals in the presence of the ligands is 18000 cm-1.
1. CFSE for [CoCl6]4- = 18000 cm-1
Now, let's consider the [CoCl4]2- complex. This complex has four chloride ligands, which means it has a tetrahedral geometry.
2. CFSE for [CoCl4]2- = ?
Since the geometry is tetrahedral, the splitting of the d orbitals is different compared to an octahedral complex like [CoCl6]4-. In a tetrahedral complex, the t2g set of d orbitals (dxy, dyz, dzx) is lower in energy, while the eg set (dx2-y2, dz2) is higher in energy.
Therefore, we can expect that the CFSE for a tetrahedral complex will be less than the CFSE for an octahedral complex with the same metal ion.
3. CFSE for [CoCl4]2- < cfse="" for="" />
From the given options, the only value that satisfies this relationship is option D, which is 8000 cm-1.
Therefore, the CFSE for [CoCl4]2- is 8000 cm-1.
The CFSE of [CoCl6]4- is given as 18000 cm-1. This means that the energy difference between the d orbitals in the presence of the ligands is 18000 cm-1.
1. CFSE for [CoCl6]4- = 18000 cm-1
Now, let's consider the [CoCl4]2- complex. This complex has four chloride ligands, which means it has a tetrahedral geometry.
2. CFSE for [CoCl4]2- = ?
Since the geometry is tetrahedral, the splitting of the d orbitals is different compared to an octahedral complex like [CoCl6]4-. In a tetrahedral complex, the t2g set of d orbitals (dxy, dyz, dzx) is lower in energy, while the eg set (dx2-y2, dz2) is higher in energy.
Therefore, we can expect that the CFSE for a tetrahedral complex will be less than the CFSE for an octahedral complex with the same metal ion.
3. CFSE for [CoCl4]2- < cfse="" for="" />
From the given options, the only value that satisfies this relationship is option D, which is 8000 cm-1.
Therefore, the CFSE for [CoCl4]2- is 8000 cm-1.
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The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000c...
= 8000cm−1
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The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will bea)6000cm−1b)16000cm−1c)18000cm−1d)8000cm−1Correct answer is option 'D'. Can you explain this answer?
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The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will bea)6000cm−1b)16000cm−1c)18000cm−1d)8000cm−1Correct answer is option 'D'. Can you explain this answer? for NEET 2024 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will bea)6000cm−1b)16000cm−1c)18000cm−1d)8000cm−1Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for NEET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will bea)6000cm−1b)16000cm−1c)18000cm−1d)8000cm−1Correct answer is option 'D'. Can you explain this answer?.
The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will bea)6000cm−1b)16000cm−1c)18000cm−1d)8000cm−1Correct answer is option 'D'. Can you explain this answer? for NEET 2024 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will bea)6000cm−1b)16000cm−1c)18000cm−1d)8000cm−1Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for NEET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The crystal field stabilisation energy (CFSE) for [CoCl6]4− is 18000cm−1. The CFSE for [CoCl4]2− will bea)6000cm−1b)16000cm−1c)18000cm−1d)8000cm−1Correct answer is option 'D'. Can you explain this answer?.
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