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The molarity of orthophosphoric acid having purity of 70% by weight and specific gravity 1.54 would be
  • a)
    11M
  • b)
    22 M
  • c)
    33 M
  • d)
    44 M
Correct answer is option 'A'. Can you explain this answer?
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The molarity of orthophosphoric acid having purity of 70% by weight an...
70% by weight 70gm H3PO4 → 100gm solution / sample
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The molarity of orthophosphoric acid having purity of 70% by weight an...
Calculation of Molarity of Orthophosphoric Acid:

Given Data:

Purity of Orthophosphoric Acid = 70% by weight
Specific Gravity of Orthophosphoric Acid = 1.54

Step 1: Calculation of Mass of Pure Orthophosphoric Acid

Let us assume the total mass of Orthophosphoric Acid to be 100 g.

Therefore, the mass of pure Orthophosphoric Acid (H3PO4) = 70 g (given purity is 70%)

Step 2: Calculation of Volume of Orthophosphoric Acid

As we know, Density = Mass/Volume

Therefore, Volume of Orthophosphoric Acid = Mass/Density

= 70/1.54

= 45.45 mL

Step 3: Calculation of Molarity of Orthophosphoric Acid

Molarity = Number of moles of solute/Volume of solution (in liters)

As the molecular weight of Orthophosphoric Acid is 98 g/mol, the number of moles of solute can be calculated as follows:

Number of moles of solute = Mass of solute/Molecular weight of solute

= 70/98

= 0.714 mol

Therefore, Molarity of Orthophosphoric Acid = 0.714/0.04545

= 15.69 M

However, the above calculated molarity is for pure Orthophosphoric Acid. But as the given Orthophosphoric Acid is only 70% pure, the actual molarity of the solution would be 70% of 15.69 M.

Actual Molarity of Orthophosphoric Acid = 0.7 × 15.69

= 11 M

Hence, the correct option is (a) 11 M.
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The molarity of orthophosphoric acid having purity of 70% by weight an...
11
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