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X-rays are reflected from a simple cubic crystal by Bragg reflection. If the density of the crystal is measured with r.m.s. error of 3 parts in 104 and if the angle made by the incident and reflected ray make with the crystal plane is 6° and is measured with an r.m.s. error 3.4 minutes of arc then what is the error in the determination of wavelength.
  • a)
    9.4 x 10-3
  • b)
    2.5 x 10-3
  • c)
    2.5 x l 0-7
  • d)
    None of these
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
X-rays are reflected from a simple cubic crystal by Bragg reflection. ...
For simple cubic crystal n = 1.
For first order reflection 2d sin θ = λ




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X-rays are reflected from a simple cubic crystal by Bragg reflection. ...
Degrees, what is the smallest wavelength that can be reliably detected using this crystal?

We can use Bragg's Law to relate the angle of reflection to the spacing between crystal planes and the wavelength of the incident X-rays:

nλ = 2d sinθ

where n is an integer (the order of the reflection), λ is the wavelength of the incident X-rays, d is the spacing between crystal planes, and θ is the angle of reflection.

For a simple cubic crystal, the spacing between crystal planes is given by:

d = a / √(h^2 + k^2 + l^2)

where a is the length of the cubic unit cell and h, k, and l are the Miller indices of the crystal plane.

Since the crystal has a density measurement with an r.m.s. error of 3 parts in 10^4, we can estimate the error in the length of the unit cell using:

Δa / a = 1/2 (Δρ / ρ)

where Δρ / ρ is the fractional error in density. Plugging in the given values, we get:

Δa / a = 1/2 (3/10^4) = 1.5/10^4

So the error in the spacing between crystal planes is:

Δd / d = 1/2 (Δa / a) = 7.5/10^4

Now we can use these values to estimate the smallest wavelength that can be reliably detected. We want to find the smallest value of λ that produces a detectable reflection, which means we want to use n = 1 in Bragg's Law. Rearranging the equation and plugging in the values, we get:

λ = 2d sinθ / n = 2a sinθ / √(h^2 + k^2 + l^2)

Δλ / λ = (Δd / d) + (Δθ / sinθ)

where Δθ is the error in the angle of reflection. Plugging in the given values, we get:

Δλ / λ = (7.5/10^4) + (0.017/0.105) = 0.182

So the smallest wavelength that can be reliably detected is:

λ_min = λ (1 + Δλ / λ) = (2.0 Å) (1 + 0.182) = 2.36 Å

Therefore, the smallest wavelength that can be reliably detected using this crystal is 2.36 Å.
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X-rays are reflected from a simple cubic crystal by Bragg reflection. If the density of the crystal is measured with r.m.s. error of 3 parts in 104 and if the angle made by the incident and reflected ray make with the crystal plane is 6° and is measured with an r.m.s. error 3.4 minutes of arc then what is the error in the determination of wavelength.a)9.4 x 10-3b)2.5 x 10-3c)2.5 x l 0-7d)None of theseCorrect answer is option 'A'. Can you explain this answer?
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