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For the four successive transition elements (Cr, Mn, Fe and Co), the stability of +2 oxidation state will be there in which of the following order?
(At. nos. Cr = 24, Mn = 25, Fe = 26, Co = 27)
  • a)
    Mn > Fe > Cr > Co
  • b)
    Fe > Mn > Co > Cr
  • c)
    Co > Mn > Fe > Cr
  • d)
    Cr > Mn > Co > Fe
Correct answer is option 'A'. Can you explain this answer?
Most Upvoted Answer
For the four successive transition elements (Cr, Mn, Fe and Co), the ...
The stability of 2 oxidation state in the four successive transition elements (Cr, Mn, Fe, and Co) can be explained based on the following factors:

1. Electronic configuration: The electronic configuration of these elements is as follows:

- Chromium (Cr): [Ar] 3d5 4s1
- Manganese (Mn): [Ar] 3d5 4s2
- Iron (Fe): [Ar] 3d6 4s2
- Cobalt (Co): [Ar] 3d7 4s2

2. Screening effect: The screening effect of the 3d electrons on the 4s electrons decreases as we move from left to right across the period. This is due to the increase in nuclear charge which attracts the 4s electrons more towards the nucleus.

3. Ionization energy: The ionization energy of the 4s electrons also increases as we move from left to right across the period. This is due to the increase in nuclear charge which makes it harder to remove an electron from the outermost shell.

Based on the above factors, the stability of 2 oxidation state in the four successive transition elements (Cr, Mn, Fe, and Co) can be explained as follows:

- Chromium (Cr): In Cr, the 3d5 electrons have a strong screening effect on the 4s electron, making it easier to remove. Also, the ionization energy of the 4s electron is relatively low. Therefore, Cr has a stable 2 oxidation state.
- Manganese (Mn): In Mn, the 3d5 electrons still have a strong screening effect on the 4s electron, but the ionization energy of the 4s electron is higher than in Cr. Therefore, Mn has a less stable 2 oxidation state compared to Cr.
- Iron (Fe): In Fe, the 3d6 electrons have a weaker screening effect on the 4s electron, and the ionization energy of the 4s electron is higher than in Mn. Therefore, Fe has a less stable 2 oxidation state compared to Mn and Cr.
- Cobalt (Co): In Co, the 3d7 electrons have an even weaker screening effect on the 4s electron, and the ionization energy of the 4s electron is the highest among the four elements. Therefore, Co has the least stable 2 oxidation state among the four elements.

Therefore, the stability of 2 oxidation state in the four successive transition elements (Cr, Mn, Fe, and Co) follows the order: Mn > Fe > Cr > Co.
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Community Answer
For the four successive transition elements (Cr, Mn, Fe and Co), the ...
The order can be explained using the idea of spin correlation. Spin correlation refers to lowering of energy for like (parallel) spins. Spin correlation leading to decrease in repulsion for electrons of like spins than for electrons of different spins is called exchange energy.
Spin correlation and its exchange energy gives an electronic configuration a special stability which is greatest for half-filled electronic configurations.
Mn2+(d5) gets stabilisation due to half-filled configuration.In Fe2+(d6) the placing of one extra electron in a subshell destabilises. Placing of 2 electrons in Co2+(d7) destabilisesit more.Cr2+(d4) has one vacant subshell. Fe2+ gets more Stabilisation compared to Cr2+ through exchange energy. So the order is as follows:
Mn > Fe > Cr > Co
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Read the passage given below and answer the following questions:The d block elements are the 40 elements contained in the four rows of ten columns (3-12) in the periodic table. As all the d block elements are metallic, the term d-block metals is synonymous. This set of d-block elements is also often identified as the transition metals, but sometimes the group 12 elements (zinc, cadmium, mercury) are excluded from the transition metals as the transition elements are defined as those with partly filled d or f shells in their compounds. Inclusion of the elements zinc, cadmium and mercury is necessary as some properties of the group 12 elements are appropriate logically to include with a discussion of transition metal chemistry. The term transition element or transition metal appeared to derive from early studies of periodicity such as the Mendeleev periodic table of the elements. His horizontal table of the elements was an attempt to group the elements together so that the chemistry of elements might be explained and predicted. In this table there are eight groups labeled I-VIII with each subdivided into A and B subgroups. Mendeleev recognized that certain properties of elements in Group VIII are related to those of some of the elements in Group VII and those at the start of the next row Group I. In that sense, these elements might be described as possessing properties transitional from one row of the table to the next.In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.Assertion (

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For the four successive transition elements (Cr, Mn, Fe and Co), the stability of +2 oxidation state will be there in which of the following order?(At. nos. Cr = 24, Mn = 25, Fe = 26, Co = 27)a)Mn > Fe > Cr > Cob)Fe > Mn > Co > Crc)Co > Mn > Fe > Crd)Cr > Mn > Co > FeCorrect answer is option 'A'. Can you explain this answer?
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